Results 181 to 190 of about 11,300,632 (342)

Epitaxial Stabilization of Ultrasmall Cu Nanoparticles With High‐Energy {110} Facets on Ti3C2 MXene for Efficient CO2‐to‐Acetate Electrocatalysis

open access: yesAdvanced Science, EarlyView.
Cu/Ti3C2 heterostructure: Cu/Ti3C2 heterostructure achieves epitaxial stabilization of high‐energy Cu(110) facets through lattice matching and electronic interaction, enabling efficient CO2 electroreduction to acetate with 42.5% Faradaic efficiency at 235 mA·cm−2. ABSTRACT The electrochemical CO2 reduction reaction (CO2RR) to multicarbon (C2+) products
Yan‐An Li   +10 more
wiley   +1 more source

Efficient Electrocatalytic Conversion of CO2 to Pure Formic Acid Solutions via Strain‐Engineered Bismuth Nanosheets

open access: yesAdvanced Science, EarlyView.
Tensile‐strained bismuth nanosheets (TS‐BiNs) achieve a formate Faradaic efficiency of 92% at −1000 mA cm−2 and enable stable production of pure formic acid (HCOOH) in a solid‐state electrolyte reactor. Theoretical calculations reveal that the introduced strain lowers the energy barrier for *OCHO intermediate formation, fundamentally enhancing the ...
Shiqi Li   +16 more
wiley   +1 more source

Bidirectional Photoswitching of a Tailored Azobenzene with Red and Far‐Red Light Involving Triplet Sensitization in an Aqueous System

open access: yesAdvanced Science, EarlyView.
The action spectrum of a tailored azobenzene is shifted toward bio‐optical window through the chemical modification of its singlet and triplet energy levels. Consequently, the bidirectional photo‐switching of azobenzene in physiological conditions is achieved when excited by red and far‐red light, which offers greater tissue penetration.
Mila Miroshnichenko   +11 more
wiley   +1 more source

Toward Predictive Theory in Single‐Atom Catalysis

open access: yesAdvanced Science, EarlyView.
A lifecycle‐oriented framework reframes modeling in single‐atom catalysis. By combining ensemble‐based descriptions with explicit validation against experimental observables, the approach defines the scope of theory across catalyst synthesis, activity, stability, and safety, clarifying where quantitative insight is possible and where interpretation ...
Andrea Ruiz‐Ferrando   +3 more
wiley   +1 more source

Chiral‐Encoded Pt‐Ir Surfaces as Apparent Spin Filter for Enhanced Oxygen Reduction

open access: yesAdvanced Science, EarlyView.
The Chiral‐Induced Spin Selectivity (CISS) effect is employed in chiral‐encoded mesoporous Platinum‐Iridium (Pt‐Ir) electrocatalysts to enhance the oxygen reduction reaction (ORR). A break in spin symmetry leads to a substantial antagonistic difference in activity (>200%) when comparing two enantiomorphs of the same electrode.
Zikkawas Pasom   +5 more
wiley   +1 more source

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