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Electrochemical oxidation of nitroylides

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1981
The mechanisms of the electrochemical oxidation of mono- and dinitroylides of S and Se on a Pt electrode in CH3CN have been studied for the first time. It was shown that the cation radical formed as intermediate was able to react with the medium with removal of an H atom and with the formation of an onium cation or to undergo decomposition. Competition
Svyatoslav A. Shevelev   +3 more
openaire   +2 more sources

Electrochemical oxidation of tryptophan

Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1986
Abstract The electrochemical oxidation of tryptophan at graphite electrodes has been studied in aqueous solutions over a wide pH range. The single voltammetric oxidation peak of tryptophan is due to an irreversible 2 e− reaction giving an extremely reactive methylene-imine intermediate.
Glenn Dryhurst   +2 more
openaire   +2 more sources

Electrochemical Oxidation of Tolterodine

Electroanalysis, 2012
AbstractThe electrochemical behavior of tolterodine, an antimuscarinic drug used to treat urge incontinence and overactive bladder, was investigated using cyclic and differential pulse voltammetry at glassy carbon electrode. Electrooxidation of tolterodine proceeds as a complex two‐step pH‐dependent process.
Vítězslav Maier   +6 more
openaire   +2 more sources

Electrochemical Oxidation of 5-Hydroxymethylfurfural with NiFe Layered Double Hydroxide (LDH) Nanosheet Catalysts

, 2018
Electrochemical oxidation of biomass-derived platform molecules can enable the production of value-added oxygenated commodity chemicals under mild conditions in a distributed fashion using renewable electricity; however, very few efficient, robust, and ...
Wu-Jun Liu   +5 more
semanticscholar   +1 more source

Electrochemical Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid (FDCA) in Acidic Media Enabling Spontaneous FDCA Separation.

ChemSusChem, 2018
2,5-Furandicarboxylic acid (FDCA) has become an increasingly desirable platform chemical to replace terephthalic acid in the production of a variety of polymeric materials, including polyethylene terephthalate.
S. Kubota, Kyoung-Shin Choi
semanticscholar   +1 more source

Electrochemical Oxidation of Atrazine and Clothianidin on Bi-doped SnO2-Ti nO2 n-1 Electrocatalytic Reactive Electrochemical Membranes.

Environmental Science and Technology, 2018
This research focused on improving mineralization rates during the advanced electrochemical oxidation treatment of agricultural water contaminants. For the first time, bismuth-doped tin oxide (BDTO) catalysts were deposited on Magnéli phase (Ti nO2 n-1 ...
Pralay Gayen   +3 more
semanticscholar   +1 more source

Electrochemical oxidation of thiobenzanilide

Electroanalysis, 1994
AbstractThe electrochemical oxidation of thiobenzanilide was studied in anhydrous acetonitrile as a model for the enzymatic oxidation of the substance. It has been found that a single electron is exchanged in the presence of 5 × 10−2 M HClO4 The oxidation products were identified as H2S, benzanilide, and 2‐phenylbenzthiazole.
Ivan Němec   +4 more
openaire   +2 more sources

Inhibition of Perchlorate Formation during the Electrochemical Oxidation of Perfluoroalkyl Acid in Groundwater

Environmental Science and Technology Letters, 2019
Perfluorooctanoic acid (PFOA) and perfluorooctanesulfonate (PFOS) are groundwater contaminants of emerging concern due to their toxicity and persistence. Currently, there are limited destructive treatment options for this type of water.
Shasha Yang   +3 more
semanticscholar   +1 more source

Stabilities, Regeneration Pathways, and Electrocatalytic Properties of Nitroxyl Radicals for the Electrochemical Oxidation of 5-Hydroxymethylfurfural

ACS Sustainable Chemistry and Engineering, 2019
2,5-Furandicarboxylic acid (FDCA) is a near-market monomer that has been identified as a viable biomass-derived replacement for petroleum-derived terephthalic acid in the synthesis of polyethylene terephthalate (PET).
Allison C. Cardiel   +2 more
semanticscholar   +1 more source

Electrochemical and photoelectrochemical water oxidation for hydrogen peroxide production.

Angewandte Chemie, 2020
Hydrogen peroxide (H 2 O 2 ), as a green fuel and oxidant, has drawn increasing attention in the energy and environment field recently. Compared with the traditional anthraquinone process, electrochemical (EC) and photoelectrochemical (PEC) synthesis of ...
Yudong Xue   +3 more
semanticscholar   +1 more source

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