Band Alignment in In‐Oxo Metal Porphyrin SURMOF Heterojunctions
Porphyrin core metalation in indium‑oxo SURMOFs enables systematic tuning of band edge positions without altering the crystal structure. First‑principles calculations reveal type‑I and type‑II heterostructures as well as multi‑junction energy cascades, establishing a modular strategy for exciton funneling and charge separation in optoelectronic ...
Puja Singhvi, Nina Vankova, Thomas Heine
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The Halogenation Effects of Electron Acceptor ITIC for Organic Photovoltaic Nano-Heterojunctions. [PDF]
Wang Y +7 more
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A previously unreported coordination motif stabilising single Fe atoms by indigo chelation and pyridyl coordination on Au(111) has been revealed. By using planar tritopic pyridyl linkers (TPyB), extended 2D porous networks of indigo3(TPyB)2Fe6 form. These networks can be crystalline or vitreous and offer an environment where individual coordination ...
Hongxiang Xu +9 more
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Production of medium-chain carboxylic acids by Megasphaera sp. MH with supplemental electron acceptors [PDF]
Byoung Seung Jeon +3 more
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Photoswitching Conduction in Framework Materials
This mini‐review summarizes recent advances in state‐of‐the‐art proton and electron conduction in framework materials that can be remotely and reversibly switched on and off by light. It discusses the various photoswitching conduction mechanisms and the strategies employed to enhance photoswitched conductivity.
Helmy Pacheco Hernandez +4 more
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Gold(III) Porphyrin Was Used as an Electron Acceptor for Efficient Organic Solar Cells. [PDF]
Cuesta V +7 more
europepmc +1 more source
A reproducible synthesis to control 3D/0D phase ratios via water‐tuned solvent–antisolvent methods is presented. Enhanced scintillation yield and ultrafast decay are achieved. Defect‐driven emission mechanisms are revealed through cathodoluminescence and radioluminescence, shedding light on the underexplored role of the 0D Cs4PbBr6 and mixed 0D/3D ...
Mario Calora +18 more
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The structure of the complex between the arsenite oxidase from Pseudorhizobium banfieldiae sp. strain NT-26 and its native electron acceptor cytochrome c552. [PDF]
Poddar N, Santini JM, Maher MJ.
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Backbone Heterojunction Photocatalysts for Efficient Sacrificial Hydrogen Production
Herein, a ‘single‐component’ organic semiconductor photocatalyst is presented in which a molecular donor is bonded to a polymer acceptor. The resultant material demonstrates exceptional photocatalytic activity for hydrogen evolution in aqueous triethylamine with an outstanding external quantum efficiency of 38% at 420 nm.
Richard J. Lyons +11 more
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Asymmetric electron acceptor enables highly luminescent organic solar cells with certified efficiency over 18. [PDF]
He C +18 more
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