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Diazadithiafulvalenes as electron donor reagents
Journal of the Chemical Society, Perkin Transactions 1, 1999Diazadithiafulvalenes act as excellent electron donors to arenediazonium salts. The diazadithiafulvalenium radical cations trap primary carbon radicals successfully. However, the diazadithiafulvalenium salts which form, undergo rapid ring fragmentation in contrast to their tetrathia counterparts.
Koizumi, T. +3 more
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Octabutoxyphthalocyanine, a new electron donor
J. Chem. Soc., Dalton Trans., 1988The preparation of the 2,3,9,10,16,17,23,24-octabutoxyphthalocyanine zinc complex (1) is described. The electron-donating groups influence the properties of the compound. The oxidation–reduction potentials studied by cyclic voltammetry in solution shift by ca.
Dieter Wöhrle, Volker Schmidt
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Metallocenes, Strong Electron Donors
2003For many years it was puzzling that metal atoms, which were not considered good Lewis acids, could form adducts with CO, considered to be a poor donor toward most Lewis acids. An example is the hexacarbonylchromium, Cr(CO)6. On the other hand, it was stressed that chromium, having 24 electrons, by accepting 6x2 electrons from 6 CO molecules, will fill ...
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Electron donors in carbocationic polymerization
Polymer Bulletin, 1989Synthese de polymeres telecheliques de tres faible masse moleculaire, a temperatures relativement ...
Miklos Zsuga, J. P. Kennedy
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Dimeric Tetrathiafulvalenes: New electron donors
Advanced Materials, 1996Organic conductors based on new classes of dimeric TTFs (e.g., see figure) are reviewed. The complexes have structures in some cases which are determined by inter‐TTF transannular interactions, leading to stretched, folded, and sandwich arrangements.
Tetsuo Otsubo +2 more
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ChemInform Abstract: Organic Electron Donors
ChemInform, 2012AbstractReview: 136 refs.
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Tetraaminoethylenes as Strong Electron Donors
Angewandte Chemie International Edition in English, 1968AbstractDepending on the nature of the electron acceptor and of the tetraaminoethylene (TAE), the electron pairs of the ethylenic double bond (A), of the nitrogen (B), or of the entire electronic system (C) of TAE react with the acceptor. Thus oxidizing agents convert TAE into the mono‐and dications TAE+ and TAE2+ by path (A); acids add on to the ...
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Free Charge Carriers in Homo-Sorted π-Stacks of Donor–Acceptor Conjugates
Chemical Reviews, 2021Meera Madhu +2 more
exaly
Ionization Potentials of Electron Donors
Nature, 1959RECENTLY, Briegleb and Czekalla1 have described a method of determining the ionization potentials (I p) of electron donors from the frequencies (ν) of the charge-transfer bands of the complexes of these donors with certain electron acceptors. This is based on a non-linear theoretical relationship between I p and ν.
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