Dioxygen Reduction at a Cu(I) Complex Supported by a Macrocyclic N3O Ligand System
A non‐reactive [CuI(14‐TMC)]+ complex is transformed to an efficient catalyst [CuI(14‐TMCO)]+ (TMCO = 4,8,12‐trimethyl‐1‐oxa‐4,8,12‐triazacyclotetradecane) for 4e−/4H+ reduction of O2 by N → O substitution. ABSTRACT CuI(14 TMCO) (1), involving a N3O‐macrocycle, reacts with O2 at cryogenic temperatures to yield an end‐on peroxodicopper(II) species.
Maximilian Schütze +3 more
wiley +1 more source
A Nonenzymatic Analogue of the Biosynthesis of Pyridoxal Vitamers. [PDF]
Nogal N, Basar AB, Minic Z, Moran J.
europepmc +1 more source
Multivalent RNA‐Cleaving Agents on a Cubic Octameric Silsesquioxane Core
RNA‐cleaving agents on a cubic octameric silsesquioxane core were synthesized and characterized. Several catalytic systems of these structures were screened using hexaribonucleotide models. The best systems were then further used to study their catalytic efficiency in cleaving a HER2 mRNA model sequence. The induced cleavage sites were also determined.
Hanni Haapsaari, Iris Tuomi, Pasi Virta
wiley +1 more source
Isocitrate Dehydrogenase Mutation Assessment in Human Glioma Using Desorption Electrospray Ionization-Multiple Reaction Monitoring. [PDF]
Shahi M +3 more
europepmc +1 more source
Tribenzotriquinacene Fused Dimers (“Fusodimers”)—Synthesis and Host–Guest Properties
Two tribenzotriquinacene units merged with each other in either syn‐ or anti‐orientation of the bowls have become accessible in a short synthesis. In contrast to the anti‐isomer, the syn‐isomer forms 1:1 host–guest complexes with both C60 and C70 in solution and in the solid state, as shown by 1H NMR spectroscopy and x‐ray diffraction.
Chun‐Fai Ng +5 more
wiley +1 more source
Phytochemical Identification of Major Compounds From Leaves of Nicotiana glauca Graham (Solanaceae) Extracts Using LC-ESI-MS/MS and Molecular Docking Analysis. [PDF]
WardaTrifa +8 more
europepmc +1 more source
Europium doping of bismuth oxido nanoclusters (BiO‐NCs) provides stable hosts for Eu3+ in an asymmetric coordination environment, which in turn results in an intense 5D0→7F0 transition and long luminescence lifetimes. Transparent hybrid materials showing characteristic red photoluminescence are accessible via radical copolymerisation of these soluble ...
Rico Thomas +5 more
wiley +1 more source
Microfluidic Electrospray Microcapsules With Spatiotemporal Release of Asiatic Acid and Baicalein Nanocarriers for Wound Healing. [PDF]
Luo Z, Zeng L, Zhu X, Zhao Y.
europepmc +1 more source

