Electron‐Deficient Linkers Enhance H2O2 Electrosynthesis in Covalent Organic Frameworks
Linker π‐conjugation modulates the electronic state of the Ni–N4 centers and their interaction with the key *OOH intermediate while preserving the primary coordination motif. NiPc‐PTDA delivers an H2O2 selectivity of 92% and a production rate of 34.8 mol gcat−1 h−1, highlighting linker electronic properties as a molecular design parameter for NiPc ...
Houting Xie +7 more
wiley +1 more source
Electrostatics and Charge Regulation Drive Phosphate Accumulation in Cationic Dendrimers. [PDF]
Blanco PM +7 more
europepmc +1 more source
Ground‐State Charge‐Transfer Doping in Donor–Acceptor Semiconducting Polymers
This work demonstrates controlled ground‐state charge‐transfer complex formation (GS‐CTC) and doping in a series of diketopyrrolopyrrole‐based donor–acceptor semiconducting polymers paired with a π‐conjugated penta‐t‐butylpentacyanopentabenzo[25]annulene “cyanostar” macrocycle. Complementary experimental techniques show how subtle molecular, electronic,
Tanner L. Smith +13 more
wiley +1 more source
Review: advancements in fibrous aerosol filtration across experimental analysis, numerical modeling, and fabrication technologies. [PDF]
Zaid MM +4 more
europepmc +1 more source
An Alhagi maurorum inspired hierarchical composite membrane (NFCu) was developed by integrating heavy metal remediation and solar‐driven interfacial evaporation in a single platform. Beyond the photothermal effect, a localized photocatalytic process is realized on the CuO surface, deepening the mechanistic understanding of light–matter–water ...
Yuqiong He +9 more
wiley +1 more source
Investigating the Effects of Charge on the Release Kinetics of Charge-Modified Peptides from Gelatin Microparticles. [PDF]
Jiang EY +8 more
europepmc +1 more source
Stereometric Molecular Engineering for Ultra‐Stable Aqueous Zinc‐Ion Batteries
Stereochemical configuration of molecular additives greatly influences interfacial adsorption at the Zn surface. The optimal tilted dual‐anchored adsorption geometry of myo‐inositol constructs a water‐deficient interface and regulates the solvation structure.
Cunxin Liu +4 more
wiley +1 more source
Electrostatic Doping of 2D Semiconductors Using Charged Dielectric Thin Films. [PDF]
Niu X +7 more
europepmc +1 more source
Covalent Functionalization of 2D Semiconductors: A Roadmap to Advanced Electronic Devices
This Review presents recent advances in the covalent functionalization strategies for two‐dimensional semiconductors and their implementation in modern technologies. Layered materials are modified through diverse molecular chemistries (e.g., thiols, diazonium salts, alkyl halides, and electron‐deficient species) to tailor their surface properties ...
Ramiro Quirós‐Ovies +2 more
wiley +1 more source
The Epichaperome Matrix Theory: A systems-level model of active molecular organization. [PDF]
Shevtsov M.
europepmc +1 more source

