Results 41 to 50 of about 7,757 (250)
Programmable Solid‐Electrolyte Interfaces for Efficient and Selective Electrochemical Hydrogenations
Angewandte Chemie, EarlyView.Poly(ionic liquid) binders are shown to actively control the electrode microenvironment, strongly enhancing electrochemical hydrogenation compared to traditional binders. The work redefines the binder as an active component of catalytic electrode design, reshaping local potential gradients and interfacial ion distribution to modulate adsorbed H ...
Anastasios Orestis Grammenos +9 more
wiley +2 more sources
Is electrosynthesis always green and advantageous compared to traditional methods?
Nature Communications, 2020 While electrosynthesis represents a green and advantageous alternative to traditional synthetic methods, electrochemical reactions still suffer from some drawbacks that require further efforts in order to fully express the potential of electricity-driven
Yong Yuan, Aiwen Lei
doaj +1 more source
Synthetic and Systems Biotechnology, 2020 Electroactive bacteria could perform bi-directional extracellular electron transfer (EET) to exchange electrons and energy with extracellular environments, thus playing a central role in microbial electro-fermentation (EF) process.
Ziying Gong +4 more
doaj +1 more source
Advanced Materials, EarlyView.Metal‐free carbon catalysts enable the sustainable synthesis of hydrogen peroxide via two‐electron oxygen reduction; however, active site complexity continues to hinder reliable interpretation. This review critiques correlation‐based approaches and highlights the importance of orthogonal experimental designs, standardized catalyst passports ...
Dayu Zhu +3 more
wiley +1 more source
Angewandte Chemie, EarlyView.Isolated Pd sites in a metallic Co matrix boost nitrate‐to‐ammonia conversion. Pd doping optimizes intermediate adsorption and reconstructs the interfacial microenvironment, promoting cation enrichment and a hydrogen‐down‐oriented water network. This dual modulation facilitates proton transfer and intermediate stabilization, enabling high ammonia ...
Qun He +6 more
wiley +2 more sources
Electrochemical Hofmann Rearrangement to Hydrazides
ChemElectroChemWe present the first electrochemical Hofmann rearrangement for the sustainable and safe synthesis of N,N‐disubstituted hydrazides from readily available ureas.
Zeyu Feng +5 more
doaj +1 more source
Xenes for Sustainable Energy: A Roadmap From First‐Principles Design to Practical Deployment
Advanced Materials Interfaces, EarlyView.Emerging 2D Xenes are advancing from theoretical predictions toward practical energy‐storage and conversion technologies through the integration of first‐principles modelling, experimental synthesis, electrochemical validation, and AI‐assisted materials design, enabling accelerated discovery of high‐performance and sustainable electrochemical systems ...
Onur Karaman, Ceren Karaman
wiley +1 more source
Angewandte Chemie, EarlyView.Using a ketal‐protected glycerol derivative (solketal) as the oxidation substrate enables site‐selective electrooxidation that suppresses C–C cleavage on non‐noble catalysts. Highly alkaline conditions promote reactive solketal alkoxide formation, weaken the Cα─H bond to facilitate dehydrogenation, and buffer local acidification, enabling a record‐high
Jiamin Wang +6 more
wiley +2 more sources
How an Anode‐Sided Gap Influences the Electrooxidation of Phenols in Flow Reactors
ChemElectroChemElectroorganic synthesis offers a sustainable way to valorize chemical building blocks through renewable energy and environmentally friendly reagents.
Jonas Wolf +6 more
doaj +1 more source
Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 products
Nature Communications, 2019 The electro-oxidative synthesis of valued chemicals offers to enhance the overall efficiency and economic viability of renewable electrosynthesis systems.
Tao-Tao Zhuang +22 more
doaj +1 more source