Enantioselective Synthesis of the Sex Pheromone of <i>Sitodiplosis mosellana</i> (Géhin) and Its Stereoisomers. [PDF]
Wang J, Li X, Zhou Y, Bian Q, Zhong J.
europepmc +1 more source
Bifenthrin Under Scrutiny: Revisiting Toxicological Evidence Amid Regulatory Gaps
ABSTRACT Despite growing health concerns, bifenthrin (BF) remains widely used for controlling agricultural and residential pests. However, different perspectives on its toxicological profile and regulatory framework warrant a revisit and update on BF regulation towards a robust risk‐safety assessment.
Caroline V. L. Moreira +10 more
wiley +1 more source
Catalytic and Enantioselective Synthesis of Inherently Chiral Saddle-Shaped Compounds by [2 + 2 + 2] Cycloaddition of 1,8-Naphthylene-Based 1,10-Diynes with Alkynoates. [PDF]
Shibata T, Nakada M, Senda K, Ito M.
europepmc +1 more source
A highly enantio‐ and diastereoselective rhodium(I)‐catalyzed defluorinative arylation of pentafluoroethyl alkenes has been developed. Both 1,1‐ and 1,2‐disubstituted alkenes were compatible leading to tetra‐ and trisubstituted fluoroalkenes, respectively, in excellent Z/E selectivities.
Hao Tan, Yihan Tang, Gavin Chit Tsui
wiley +1 more source
De Novo Enantioselective Synthesis of Hexafluorinated d-Glucose. [PDF]
Depienne S +4 more
europepmc +1 more source
The parent 5,5′‐binaphtho[2,1‐d]isoxazole and its 3,3′‐dimethyl and 3,3′‐diphenyl derivatives are synthesized via condensation of the respective dicarbonyl compounds with hydroxylamine, followed by cyclodehydration of the resulting dioximes. The dicarbonyl precursors are obtained through 4‐ or 6‐step sequences from 1‐naphthol or 1‐naphthaldehyde ...
Marek Surowiec +6 more
wiley +1 more source
Catalytic Enantioselective Synthesis of 1,4-(Hetero) Dicarbonyl Compounds through α-Carbonyl Umpolung. [PDF]
Friedmann T +4 more
europepmc +1 more source
Cu2O/Cu Chiral Catalysts for Highly Selective Solar‐Assisted CO2‐to‐CO Electroreduction
To address the poor target‐product selectivity of the eCO2RR, breakthrough approaches based on the chiral‐induced spin selectivity phenomenon enhance the Faradaic efficiency (FE) for target hydrocarbons, such as CO. To induce this spin polarization strategy in Cu2O/Cu catalysts, it is proposed using amine‐based intermediate organic molecules with ...
Hyungsoo Lee +13 more
wiley +1 more source
Enantioselective Synthesis of the Guaipyridine Alkaloid (+)- and (-)-Cananodine. [PDF]
Holliday HM +3 more
europepmc +1 more source
Recent Advances in Heterogeneous Frustrated Lewis Pair: Synthesis, Characterization, and Catalysis
This review provides a concise analysis of heterogeneous frustrated Lewis pair (FLP) chemistry, focusing on their synthesis, characterization, and application in small‐molecule activation. It highlights current challenges in developing solid FLP systems and explores promising advancements through emerging technologies, offering critical insights into ...
Jiasi Li +2 more
wiley +1 more source

