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Enantioselective Synthesis of Tetrahydroquinolines by Borrowing Hydrogen Methodology: Cooperative Catalysis by an Achiral Iridacycle and a Chiral Phosphoric Acid.

Angewandte Chemie, 2017
We report herein the highly enantioselective synthesis of 2-substituted tetrahydroquinolines through borrowing hydrogen, a process recognized for its environmentally benign and atom-economical nature.
C. Lim, T. Quach, Yu Zhao
semanticscholar   +1 more source

Enantioselective Synthesis of [6]Carbohelicenes.

Journal of the American Chemical Society, 2017
The use of α-cationic phosphonites derived from TADDOL as ancillary ligands has allowed a highly regio- and enantioselective synthesis of substituted [6]carbohelicenes by sequential Au-catalyzed intramolecular hydroarylation of diynes.
E. González-Fernández   +5 more
semanticscholar   +1 more source

Highly Enantioselective Synthesis of Indolines: Asymmetric Hydrogenation at Ambient Temperature and Pressure with Cationic Ruthenium Diamine Catalysts.

Angewandte Chemie, 2016
A highly enantioselective synthesis of indolines by asymmetric hydrogenation of 1H-indoles and 3H-indoles at ambient temperature and pressure, catalyzed by chiral phosphine-free cationic ruthenium complexes, has been developed.
Zhusheng Yang   +4 more
semanticscholar   +1 more source

Enantioselective Synthesis of Dihydrospiro[indoline-3,4'-pyrano[2,3-c]pyrazole] Derivatives via Michael/Hemiketalization Reaction.

Organic Letters, 2016
A new bifunctional squaramide organocatalyst derived from L-proline mediated the first enantioselective synthesis of dihydrospiro[indoline-3,4'-pyrano[2,3-c]pyrazole] derivatives in excellent enantioselectivity by reacting pyrazolones with isatylidine β ...
Nandarapu Kumarswamyreddy, V. Kesavan
semanticscholar   +1 more source

Brønsted Acid Catalyzed [3+2]-Cycloaddition of 2-Vinylindoles with In Situ Generated 2-Methide-2H-indoles: Highly Enantioselective Synthesis of Pyrrolo[1,2-a]indoles.

Chemistry, 2016
Pyrrolo[1,2-a]indoles are privileged structural elements of many natural products and pharmaceuticals. An efficient one-step process for their highly diastereo- and enantioselective synthesis, comprising a direct [3+2]-cycloaddition, has been developed ...
K. Bera, C. Schneider
semanticscholar   +1 more source

Brønsted Acid Catalyzed [3 + 2]-Cycloaddition of Cyclic Enamides with in Situ Generated 2-Methide-2H-indoles: Enantioselective Synthesis of Indolo[1,2-a]indoles.

Organic Letters, 2016
An efficient formal [3 + 2]-cycloaddition toward the highly diastereo- and enantioselective synthesis of indolo[1,2-a]indoles is disclosed. A chiral BINOL-derived phosphoric acid catalyzed the highly enantioselective conjugate addition of cyclic enamides
K. Bera, C. Schneider
semanticscholar   +1 more source

Enantioselective Synthesis on the Solid Phase

ChemInform, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Herbert Waldmann, Torben Leßmann
openaire   +3 more sources

Enantioselective Synthesis of Paraconic Acids.

ChemInform, 2002
AbstractFor Abstract see ChemInform Abstract in Full Text.
Rakeshwar B. Chhor   +5 more
openaire   +4 more sources

An enantioselective synthesis of (−)-alloyohimbane

Tetrahedron Letters, 1988
AbstractThe key step in the synthesis of the alkaloid (VII) mentioned in the title is the photolytic rearrangement of the spiro‐fused oxaziridines (III) to give the decahydroisoquinolinones (IV) and (V).
openaire   +3 more sources

Enantioselective Synthesis of (+)-Juvabione [PDF]

open access: possibleThe Journal of Organic Chemistry, 2000
Eike J. Bergner, Günter Helmchen
openaire   +2 more sources

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