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New Horizons in Chemical Functionalization of Endohedral Metallofullerenes [PDF]
Molecules, 2020 This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years.
Michio Yamada +3 more
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Recent advances in endohedral metallofullerenes [PDF]
Fundamental ResearchFullerenes are a collection of closed polycyclic polymers consisting exclusively of carbon atoms. Recent remarkable advancements in the fabrication of metal-fullerene nanocatalysts and polymeric fullerene layers have significantly expanded the potential ...
Wenting Cai +3 more
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Recent Progress on the Functionalization of Endohedral Metallofullerenes
Inorganics, 2023 Functionalization of endohedral metallofullerenes (EMFs) plays an important role in exploring the reactivity of EMFs and stabilizing missing EMFs, thus conferring tunable properties and turning EMFs into applicable materials.
Xianming Zhang, Xingyan Liu, Fei Jin
exaly +4 more sources
Inorganics, 2023 A novel Non-Isolated-Pentagon-Rule (non-IPR) isomer of thorium-based endohedral mono-metallofullerenes (mono-EMFs), Th@C1(17418)-C76, was successfully synthesized and characterized using MALDI-TOF mass spectroscopy, single-crystal X-ray diffraction, UV ...
Yunpeng Xia +4 more
doaj +1 more source
International Journal of Electrochemical Science, 2016 We isolated and purified three disamarium metallofullerenes of known structure, Sm2@D2(35)-C88, Sm2@C1(21)-C92 and Sm2@D3d(822)-C104, by the reported method.
Jie Chen +4 more
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Lu-Lu Bond in Lu2@C60 Metallofullerenes
Inorganics, 2023 This study on Lu2@C60 isomers provides insights into the metal–metal bond through the confinement effect of fullerene cages. Density functional theory calculations were used to study the nature of the Lu-Lu bond in two stable endohedral metallofullerenes
Yaoxiao Zhao +3 more
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Energies, 2023 A considerable potential advantage of manufacturing electric and thermoelectric devices using endohedral metallofullerenes (EMFs) is their ability to accommodate metallic moieties inside their cavities.
Majed Alshammari +3 more
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Успехи физики металлов, 2022 We study the experimental and theoretical works concerned with the description of state-of-the-art methods for the preparation of iron-containing endohedral metallofullerenes (EMF), as well as works, which dispute such results due to the extremely low ...
Z. A. Matysina, Ol. D. Zolotarenko, O. P. Rudakova, N. Y. Akhanova, A. P. Pomytkin, An. D. Zolotarenko, D. V. Shchur, M. T. Gabdullin, M. Ualkhanova, N. A. Gavrylyuk, A. D. Zolotarenko, M. V. Chymbai, and I. V. Zagorulko
doaj +1 more source
TmCN@C82: Monometallic Clusterfullerene Encapsulating a Tm3+ Ion
Inorganics, 2023 Metal cyanide clusterfullerenes (CYCFs) are formed via the encapsulation of a single metal atom and a cyanide unit inside fullerene cages, endowing them with excellent properties in various applications.
Huichao Zhang +6 more
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Enantioselective Synthesis of Endohedral Metallofullerenes
Journal of the American Chemical Society, 2011 Endohedral metallofullerenes are promising materials in biomedical and material sciences. In particular, they are of interest as agents for magnetic resonance imaging (MRI), photovoltaic devices, and semimetallic components. The synthesis of chiral endofullerenes represents one step further in the potential use of these carbon allotropes; however, this
Sawai K. +10 more
openaire +3 more sources