Results 51 to 60 of about 4,816 (182)
ChemPhysChem, Volume 26, Issue 4, February 16, 2025.The 3‐centre metal–metal bonding in the tri‐actinide clusters [An₃Cl₆]z (z=1–6) and [An₃Cl₆Cp₃]z (z=−2–+3; An=Ac–Pu) is explored using computational chemistry methods. The studied clusters have 2, 1 or 0 electrons in the 3‐centre MOs and their electronic structures and geometries are discussed.
Josef Tomeček +2 more
wiley +1 more source
Advanced Functional Materials, Volume 34, Issue 49, December 2, 2024.Fullerene‐based immunomodulatory nanomaterials have a dual immunomodulatory mechanism. They activate the immune system after immunosuppression, giving them powerful roles in tumor immunotherapy and tumor‐enhancing immunotherapy. In addition, fullerene nanomaterials inhibit over‐activated immunity, developing different strategies to suppress related ...
Mingming Zhen +3 more
wiley +1 more source
Precision Chemistry of Metallofullerenes and Graphene: Recent Advances
ChemPlusChem, Volume 89, Issue 11, November 2024.Precision chemistry of synthetic carbon allotropes including fullerene and graphene is at the forefront of nanocarbons chemistry. This minireview provides a concise overview of the latest advancements in the precision chemistry of metallofullerene and graphene, underlining the challenges and prospects for ongoing research.
Xueyi Chang, Muqing Chen, Tao Wei
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, 2016 The first successful production and chromatographic isolation of dysprosium endohedral metallofullerenes are reported. A series of 18 endohedral fullerenes have been separated and isolated having mainly two dysprosium metals engaged in a range of ...
Nikos Tagmatarchis (1617898) +1 more
core +1 more source
Encapsulated Atomic Hydrogen in Octamethyl‐POSS Cages: A Pulsed EPR Study
ChemPlusChem, Volume 89, Issue 11, November 2024.The electron spin relaxation properties and hyperfine interactions of atomic hydrogen trapped in octamethyl‐POSS cages are studied by advanced EPR methods. Despite the typical shortening of the electron spin coherence time T2 at low temperatures due to methyl rotation, this species exhibits key spectroscopic properties that could be harnessed to ...
G. Mitrikas
wiley +1 more source
Yttrium-Containing Endohedral Metallofullerenes: Synthesis and Extraction
, 2017 Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала.Yttrium-containing endohedral metallofullerenes are synthesized in an RF arc discharge in the helium flow with embedded Y2O3.
Tomashevich, E. V. +12 more
core +2 more sources
(Invited) Hydrogenation of Endohedral Metallofullerenes [PDF]
ECS Meeting Abstracts, 2013 Abstract not Available.
Jianyuan Zhang, Wujun Fu, Harry C. Dorn
openaire +1 more source
Functionalization Studies of C₆₀ and Synthetic Approaches to Endohedral Metallofullerenes [PDF]
, 1998 Two strategies aimed at the synthesis of endohedral metallofullerenes are presented. They have required the exploration of the surface chemistry of C60 as well as the development of efficient syntheses of highly unsaturated acetylenic cyclophanes.
Rubin, Yves, Yves Rubin
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Exohedral Diels‐Alder Reactivity of Endohedral Metallofullerene C36
Chemistry – A European Journal, Volume 30, Issue 58, October 17, 2024.The preferential position of 3d metal atoms inside the C36 cage and their effect on exohedral Diels‐Alder reactivity is reported in comparison with the empty C360 and C362− cages. Among all [5‐5], [6‐5] and [6 6] C−C bonds the [5‐5] bond is the most reactive bond in both the empty C36 and metallofullerene M@C36.
Athul Santha Bhaskaran +4 more
wiley +1 more source
Superatomic‐based chirality: Asymmetric structures constructed by superatoms
Aggregate, Volume 5, Issue 4, August 2024.The assembly of chiral structures using superatoms as building blocks is reported for the first time. The success of this assembly depends on the bonding properties of superatoms, leading to the emergence of a distinct form of chirality named “superatomic‐based chirality”.
Famin Yu +4 more
wiley +1 more source