Results 81 to 90 of about 4,816 (182)
10.1039/C4FD00096JTwo different interpretations have been recently proposed to rationalize the stabilization of some hosting cages in endohedral metallofullerenes as a consequence of the larger localization of the negative charge on pentagonal rather ...
Rodríguez-Fortea, A., Poblet, J.M.
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Near-Infrared Photoluminescence Properties of Endohedral Mono- and Dithulium Metallofullerenes
The optical properties of endohedral metallofullerene molecules can be tuned by changing the fullerene size as well as the number of metal atoms inside the fullerene cages.
Toshiki Sugai (2461003) +7 more
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We have modified the conventional procedures for endohedral metallofullerene production by (1) arc discharge of carbon rods containing carbon-coated rare-earth carbides and (2) ultrasonic Soxhlet extraction (USE) of the raw soots. The enhanced efficiency
Yang, S. +3 more
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SYNTHESIS, ELECTRONIC STRUCTURE, AND REACTIVITY OF ENDOHEDRAL METALLOFULLERENES AND OTHER ENDOHEDRAL CARBON NANOSTRUCTURES [PDF]
The discovery in 1985 of fullerenes combined with the development of STM beginning in 1981 is credited as the starting point of the current nanoscience revolution.
Elliott, Bevan
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The Role that Internal Metals Play in Endohedral Metallofullerenes
Position and motion of the internal metals in endohedral metallofullerenes show significant influences, via strong metal-cage interactions, on the structures and properties, especially the chemical reactivity, on the whole molecules.
Xing Lu +6 more
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Endohedral mono-metallofullerenes are the prototypes to understand the fundamental nature and the unique interactions between the encapsulated metals and the fullerene cages.
Alain Rafael Puente Santiago (11428128) +8 more
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Based on density-functional theory and non-equilibrium Green's function calculations, we demonstrate that endohedral metallofullerenes (EMFs) are reactive to open-shell gases, and therefore have the potential application as selective open-shell gas ...
XY Cui (9855974) +3 more
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Isolation and XPS characterization of endohedral metallofullerenes Dy@C-82 and Er@C-82
Endohedral metallofullerenes DY@C-32 and Er@C-82 have been produced by the are-discharge method and isolated by high performance liquid chromatography (HPLC). The isolated metallofullerenes Dy@C-82 and Er@C-82 as well as the metal tri-chlorides DyCl3 and
Yang, SH, Huang, HJ, Ding, JQ
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Chemical Reactivity and Regioselectivity of Trimetallic Nitride Endohedral Metallofullerenes
Endohedral metallofullerenes (EMF) have attracted increasing attention during past decades for their potential applications in the fields of biomedicine and nanomaterials.
Cai, Ting
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Electrode-Supported Endohedral Metallofullerenes: Insights into the Confined Internal Dynamics
Endohedral metallofullerenes show great promise as molecular-scale memory units due to their robust architecture and protective capability for encapsulated atoms.
Xinyao Wang (10068460) +3 more
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