Results 101 to 110 of about 5,440 (254)

Nutritional strategies to reduce enteric methane emissions

, 2016
Methane (CH4) emissions from ruminants are responsible for approximately 50% of the greenhouse gas (GHG) emissions associated with agriculture in Scotland. Reducing the emissions intensity (EI; the amount of GHG emitted per unit of meat or milk produced) of ruminants is, therefore, key to reducing agriculturalemissions in Scotland.
Rooke, JA, Miller, G A, Flockhart, JF, McDowell, MM, MacLeod, M   +4 more
openaire   +1 more source

A New Spin on Photocatalysis: Vortex Fluidic‐Driven Photooxidations Enabled by Solution‐Processable Microporous Polymers

Chemistry – A European Journal, EarlyView.
Newly developed polymers with intrinsic microporosity (PIMs) were combined with benzo[c][1,2,5]thiadiazole (BTZ) to be used as visible light photocatalytic coatings on the Vortex Fluidic Device (VFD). The VFD's rapid rotation and continuous flow capabilities enhanced singlet oxygen and superoxide radical reactions, achieving a dramatic eightfold ...
Leonardo Amicosante, Fiona R. Gordon, Dominic Taylor, Neil B. McKeown, Daniel M. Jubb, Stuart R. Kennedy, Marc A. Little, Filipe Vilela, Colin L. Raston, Scott J. Dalgarno   +9 more
wiley   +1 more source

Characteristics of rumen microbiota and Prevotella isolates found in high propionate and low methane-producing dairy cows

Frontiers in Microbiology
Ruminal methane production is the main sink for metabolic hydrogen generated during rumen fermentation, and is a major contributor to greenhouse gas (GHG) emission.
Takumi Shinkai, Shuhei Takizawa, Osamu Enishi, Koji Higuchi, Hideyuki Ohmori, Makoto Mitsumori   +5 more
doaj   +1 more source

Controlled Formation and Unusual Reactivity of Cyanohexatriyne (HC7N), a Synthetically Challenging Interstellar Cyanopolyyne

Chemistry – A European Journal, EarlyView.
First controlled formation of cyanohexatriyne (HC7N) is achieved using a cobalt–alkyne masking strategy that overcomes the intrinsic instability of nitrile‐substituted polyynes. The approach enables spectroscopic validation of HC7N and reveals its pronounced electrophilicity through a selective conjugate addition with diethylamine.
Léa Lefrançois, Mano Cremer, Thierry Roisnel, Jean‐Claude Guillemin, Yann Trolez   +4 more
wiley   +1 more source

Perspective: Enteric methane mitigation and its impact on livestock hydrogen emissions

Journal of Dairy Science
: In a hydrogen-based economy future, hydrogen leakage is becoming an environmental concern. Ruminants naturally produce small amounts of hydrogen, which is emitted in the environment along with other fermentation gases, such as the GHG methane and ...
Alexander N. Hristov, Susan Solomon
doaj   +1 more source

Ni2‐Imido Bispincer Platforms: Cooperative Reactivity Enabled Through Substrate Addition Across a Ni2N Unit

Chemistry – A European Journal, EarlyView.
Ni2 bispincer complexes with an embedded central imido anchor are presented. The bispincer complexes leverage the high basicity of imido ligands to facilitate 1,2 addition of weak B─H and Si─H bonds, resulting in hydrido–amido complexes and resultingly a contortion of a Ni─Ni sigma bond to form an S = 1 species. The 1,2 addition is proposed to serve as
David de los Santos, Kritika Gour, Manar M. Shoshani   +2 more
wiley   +1 more source

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

Chemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz, Sven Schaefer, Oksana Storcheva, Gabriele Raudaschl‐Sieber, Johannes Bitzer, Wolfgang Kleist, Klaus Köhler   +6 more
wiley   +1 more source

Synthesis of Tris(indol‐3‐yl)methanes From Indoles, CO2, and Dimethylphenylsilane With BPh3: Two‐Step Construction of π‐Conjugated Systems

Chemistry – A European Journal, EarlyView.
Tris(indol‐3‐yl)methanes were synthesized from indoles, CO2, and PhMe2SiH in the presence of BPh3 in acetonitrile at 50°C. One product, tris(4‐bromo‐1‐methylindol‐3‐yl)methane, underwent a palladium‐catalyzed cascade reaction for the formation of a novel polycyclic heteroaromatic compound, where the methine C(sp3) atom originating from CO2 was ...
Sha Li, So Saibara, Reito Yasui, Kazuto Takaishi, Natsumi Nitta, Tadashi Ema   +5 more
wiley   +1 more source

First Operation Results of a Methanol Demonstration Plant With Real Steel Mill Gases

Chemie Ingenieur Technik, EarlyView.
A demonstration plant with industrial setup regarding length, diameter, boiling water cooling system and gas recycle was initially operated with cleaned blast furnace gas and compared with earlier experiments with bottle gases. Dynamic disturbances from the steel mill and gas cleaning unit were noticed and could be compensated by the control system ...
Johannes Michael Voß, Tim Schulzke
wiley   +1 more source

Selective Non‐Catalytic Reduction of NOx in the Exhaust Gas of Small Wood Gasification Boilers

Chemie Ingenieur Technik, EarlyView.
Kinetic studies of the SNCR reaction were conducted to investigate NOx reduction in the exhaust gas of small‐scale wood gasification boilers. Both the experimental results and the derived global kinetic model indicate that SNCR can achieve a significant reduction in NOx emissions under typical operating conditions. ABSTRACT The gas‐phase reaction of NO
Alexander Groß, Sven Kureti
wiley   +1 more source