Results 221 to 230 of about 11,102,711 (256)

Rare‐Earth Multivariate Metal–Organic Frameworks: Cationic Radius Biased Compositional Control and Property Tuning

Angewandte Chemie, EarlyView.
A family of multivariate metal–organic frameworks, UoB‐116(Ln), can be prepared using up to 16 different metals, revealing the ability to tune properties through compositional control. ABSTRACT The synthesis of a multivariate metal–organic framework (MTV‐MOF) family, [Ln(DNNDI)1.5]n (UoB‐116), is reported (DNNDI: N,N'‐bis(dinicotinate)‐1,4,5,8 ...
Adnan Ishaq, Joseph O. Ogar, Asif Raza, Musa M. Mahmud, Jacob L. Brownlee, Danielle E. Schier, Stephen P. Argent, Lucy Clark, Soumya Mukherjee, Neil R. Champness   +9 more
wiley   +1 more source

Design of a metabolically-stable peptide therapeutic with triple-hormone-receptor agonist activity. [PDF]

J Comput Aided Mol Des
Vishnoi S, Hudson S, Bhattacharya S, Thompson D.   +3 more
europepmc   +1 more source

Polyproline: A Synthetic Polypeptide With Unique Properties

Angewandte Chemie, EarlyView.
Poly‐L‐proline is a unique polypeptide distinguished by its well‐defined secondary structures and unusual thermal behavior. This mini review highlights recent advances in the synthesis of poly‐L‐proline by N‐carboxyanhydride (NCA) polymerization, the formation of structurally defined architectures and nanostructures, and emerging strategies that ...
Rosanna Le Scouarnec, Josué M. Galindo, Colin Bonduelle, Andreas Heise   +3 more
wiley   +1 more source

A Robust Methodology to Elucidate Kinetics of Room Temperature Electrochemical Propane Adsorption on Platinum. [PDF]

JACS Au
Bhadouria A, Parab DE, Gonzalez Morales KD, Li C, Zea-Villa DA, Huang PC, Greeley J, Tackett BM.   +7 more
europepmc   +1 more source

High‐Tg Polythioesters From Isomerization Ring‐Opening Polymerization of a Renewable Oxanorbornane‐Fused Thionolactone

Angewandte Chemie, EarlyView.
A biobased tricyclic thionolactone undergoes selective isomerization ring‐opening polymerization to yield a high‐molecular‐weight polythioester with an exceptionally high Tg of 171°C, exceeding that of the analogous polyester. The polythioester efficiently depolymerizes through backbiting, while its hydrolysis and methanolysis reveal the critical ...
Eva Harsevoort, Henk‐Jan Akkerman, Martin Lutz, Arnaud Thevenon, Pieter C. A. Bruijnincx   +4 more
wiley   +1 more source

Coarse‐Grained Simulations Rationalize Thermosensitivity and Hydrolytic Degradation of Vinyl Copolymers Obtained by Radical Ring‐Opening Polymerization

Angewandte Chemie, EarlyView.
Coarse‐grained (CG) molecular dynamics simulations were used to predict the upper critical solution temperature of copolymers obtained by radical ring‐opening copolymerization of cyclic ketene acetals and vinyl monomers, and to account for their unique degradation kinetics under physiological conditions by evaluating the solvation of their ester groups.
Ping Gao, Yingmin Jiang, Tâp Ha‐Duong, Julien Nicolas   +3 more
wiley   +1 more source

A Half-Century of Supramolecular Thermodynamics: A Retrospective of Our Multidisciplinary Approach. [PDF]

Molecules
Danil de Namor AF, Al Hakawati N.
europepmc   +1 more source

Radical, Not Ionic: The Mechanochemical Zincke Nitration of Phenols

Angewandte Chemie, EarlyView.
Mechanochemistry recasts the classical Zincke nitration as an open‐shell process. Liquid‐assisted vibrational milling of phenols with in situ HNO2 delivers direct and ipso nitration across 50 substrates, while atmosphere, NOx‐transfer, EPR and DFT evidence expose a phenoxyl‐radical/NO2 manifold underlying this historically ionic transformation ...
Roberto Scipione, Francesco Basoccu, Pietro Caboni, Francesca Sardu, Enrico Podda, Marco Lucarini, Massimiliano Arca, Andrea Porcheddu   +7 more
wiley   +1 more source