Results 131 to 140 of about 40,186 (336)

Scaling laws for ring-shaped beam profiles in laser-based powder bed fusion of metals

open access: yesAdvances in Industrial and Manufacturing Engineering
The application of alternative beam shapes is a current research trend to stabilize and accelerate the laser-based powder bed fusion of metals process. Although many publications show a reduced process dynamic and an enlargement of the process window for
Jonas Grünewald   +2 more
doaj   +1 more source

Engineering Active Metal and Nonmetal Sites in Porous Structures of Metal‐Hydroxide Clusters for Enhanced D2/H2 Uptake and Separation

open access: yesAdvanced Science, EarlyView.
Two supramolecular assembly frameworks, constructed from metal‐hydroxide clusters, are synthesized via coordination‐driven self‐assembly mediated by Co2+ and Cu2+ metal centers. One of them demonstrates exceptional D2 and H2 uptake capabilities, achieving the second‐highest uptake capacity for D2.
Zhuozhou Xie   +11 more
wiley   +1 more source

THERMODYNAMICS OF THE MIXING PROCESS OF SEVERAL SODIUM SULFONAMIDES IN ETHANOL + WATER COSOLVENT MIXTURES ESTUDIO TERMODINÁMICO DEL PROCESO DE MEZCLA DE ALGUNAS SULFONAMIDAS SÓDICAS EN MEZCLAS COSOLVENTES ETANOL + AGUA

open access: yesVitae, 2011
Sodium sulfonamides have been extensively used for the treatment of certain infections caused by several types of microorganisms. Although sulfonamides are still widely used in therapeutics, the physicochemical information about their aqueous solutions ...
Daniel R DELGADO   +2 more
doaj  

Label‐Free and Immobilization‐Free Protein‐Binding Assays by Ultraviolet Transient Absorption Microscopy

open access: yesAdvanced Science, EarlyView.
A femtosecond UV pump–probe microscope resolves binding‐induced changes in protein excited‐state dynamics and converts these intrinsic contrasts into an equilibrium affinity readout. By probing tryptophan responses directly in solution, the approach enables quantitative determination of dissociation constants without labeling or immobilization ...
Jianghao Shen   +5 more
wiley   +1 more source

Photochemical N‐dealkylation of Tertiary Amines Coupled With Photocharging of Poly(Heptazine Imides)

open access: yesAngewandte Chemie, EarlyView.
Protonated poly(heptazine imide) (H‐PHI) functions as an energy reservoir, thereby facilitating the endothermic dealkylation of triethylamine through a proton‐coupled two‐electron transfer (PC2ET) process. The extent of photocharging is quantitatively described by a molecular‐level descriptor, Ne:Nhept, providing a direct correlation between stored ...
Jingru Zhuang   +6 more
wiley   +2 more sources

Phase Diagrams and Piezoelectric Properties of Wurtzite Al1−x−yScxGdyN Heterostructural Alloys

open access: yesAdvanced Science, EarlyView.
This study demonstrates ferroelectricity and piezoelectric properties improvement of quaternary wurtzite Al1−x−yScxGdyN${\rm Al}_{1-x-y}{\rm Sc}_x{\rm Gd}_y{\rm N}$ films, guided by density functional theory calculations. Wurtzite Al1−x−yScxGdyN${\rm Al}_{1-x-y}{\rm Sc}_x{\rm Gd}_y{\rm N}$ films have a high optical bandgap, enhanced piezoelectric ...
Julia L. Martin   +11 more
wiley   +1 more source

Geometry Controls Confined Water Dynamics in Lipidic Mesophases

open access: yesAngewandte Chemie, EarlyView.
An archaeal‐inspired lipidic mesophase allows precise control of interfacial curvature and water‐channel connectivity. Combining structural, thermodynamic, and ultrafast spectroscopies, we reveal that curvature governs the structure and reorientation dynamics of confined water, establishing a molecular‐level link between topology and dynamics in soft ...
Sara Catalini   +7 more
wiley   +2 more sources

Record‐High Latent Heat, Ultra‐Fast Relaxation and Closed‐Loop Recycling Double‐Brush Polymer Networks for Self‐Adaptive Thermal Interface Management

open access: yesAdvanced Science, EarlyView.
By grafting dense long double‐brush chains, we synthesized bottlebrush networks with high theoretical enthalpy. Their low entanglement, combined with dynamic bonds, promotes crystalline domain reorganization and minimizes enthalpy loss, achieving a record enthalpy of 240.7 J·g−1.
Qiguang Liu   +7 more
wiley   +1 more source

Melt-quenched carboxylate metal–organic framework glasses

open access: yesNature Communications
Although carboxylate-based frameworks are commonly used architectures in metal-organic frameworks (MOFs), liquid/glass MOFs have thus far mainly been obtained from azole- or weakly coordinating ligand-based frameworks. This is because strong coordination
Minhyuk Kim   +5 more
doaj   +1 more source

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