Results 11 to 20 of about 165,932,823 (169)

Piezoelectric crystal microbalance measurements of enthalpy of sublimation of C2–C9 dicarboxylic acids [PDF]

open access: yesAtmospheric Measurement Techniques, 2016
We present here a novel experimental set-up that is able to measure the enthalpy of sublimation of a given compound by means of piezoelectric crystal microbalances (PCMs).
F. Dirri   +3 more
doaj   +2 more sources

Thermochromatography of Heavy Actinides - Determination of the Sublimation Enthalpy of Es [PDF]

open access: yes, 1997
The adsorption of Cf, Es, and Fm on several metals was studied thermochromatographically. In all systems investigated Es is adsorbed between the Cf and Fm, due to the increasing metallic divalency in the second half of the actinide series.
Schädel, Μ.   +5 more
core   +3 more sources

Calculation of Crystal-Solution Dissociation Constants

open access: yesBiomolecules, 2022
The calculation of dissociation constants is an important problem in molecular biophysics. For such a calculation, it is important to correctly calculate both terms of the binding free energy; that is, the enthalpy and entropy of binding.
Sergiy O. Garbuzynskiy   +1 more
doaj   +1 more source

Phase Transitions Equilibria of Five Dichlorinated Substituted Benzenes

open access: yesMolecules, 2023
This work reports an experimental study aiming to determine the thermodynamic properties of five chlorinated compounds with environmental impact. The vapor pressures of the crystalline phases of three isomers of dichlorobenzoic acid (2,4-, 2,5-, and 2,6-)
Ana R. R. P. Almeida   +2 more
doaj   +1 more source

Thermodynamic properties of L-menthol in crystalline and gaseous states

open access: yesТонкие химические технологии, 2020
Objectives. Menthol causes a cooling sensation and reduces the nerve activity when it is applied locally, ingested, or inhaled. This feature explains its extensive use as both an aromatizer and a flavoring agent in food manufacturing, tobacco industry ...
A. V. Blokhin, Ya. N. Yurkshtovich
doaj   +1 more source

On the Enthalpy of Formation and Enthalpy of Sublimation of Dihydroxylammonium 5,5′‐bitetrazole‐1,1′‐dioxide (TKX‐50) [PDF]

open access: yes, 2023
The thermodynamic characterization of dihydroxylammonium 5,5′-bitetrazole-1,1′-dioxide (TKX-50) was reinvestigated. Although TKX-50 is one of the most promising new-generation energetic materials, contradictory reports are found in the literature with ...
Ana L. R. Silva   +9 more
core   +1 more source

Isavuconazole: Thermodynamic Evaluation of Processes Sublimation, Dissolution and Partition in Pharmaceutically Relevant Media

open access: yesMolecules, 2021
A temperature dependence of saturated vapor pressure of isavuconazole (IVZ), an antimycotic drug, was found by using the method of inert gas-carrier transfer and the thermodynamic functions of sublimation were calculated at a temperature of 298.15 K. The
Marina Ol’khovich   +3 more
doaj   +1 more source

Calculation of Five Thermodynamic Molecular Descriptors by Means of a General Computer Algorithm Based on the Group-Additivity Method: Standard Enthalpies of Vaporization, Sublimation and Solvation, and Entropy of Fusion of Ordinary Organic Molecules and Total Phase-Change Entropy of Liquid Crystals

open access: yesMolecules, 2017
The calculation of the standard enthalpies of vaporization, sublimation and solvation of organic molecules is presented using a common computer algorithm on the basis of a group-additivity method.
Rudolf Naef, William E. Acree
doaj   +1 more source

Structure and stability of aquotetrafluorouranyl(VI) in the solid state - Density functional study of [UO2F4(H2O)][NMe4]2·2H2O1,2 [PDF]

open access: yes, 2009
Periodic density functional computations have been performed for solid [UO2F4(H2O)][NMe4]2·2H(2)O at the BLYP level. A model with disordered fluoro and aquo ligands in the uranyl anion is significantly lower in energy than one with a symmetrical ...
Buehl, Michael
core   +1 more source

Characterization of the Sublimation and Vapor Pressure of 2-(2-Nitrovinyl) Furan (G-0) Using Thermogravimetric Analysis: Effects of Complexation with Cyclodextrins

open access: yesMolecules, 2015
In the present work, the sublimation of crystalline solid 2-(2-nitrovinyl) furan (G-0) in the temperature range of 35 to 60 °C (below the melting point of the drug) was studied using thermogravimetric analysis (TGA).
Vivian Ruz   +4 more
doaj   +1 more source

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