Hypercrosslinked Polymer Supported Sulfonic Acids For Esterification of Carboxylic Acids [PDF]
This work focused on the catalytic performance of hypercrosslinked sulfonic acid for esterification of carboxylic acids. The commercially available hyercrosslinked poly(styrene-divinylbenzine)sulfonic acids, Purolite D5081 and D5082 were found to be ...
Zhu, Qingyu
core +3 more sources
White‐Light‐Mediated Imidazole Catalysis Toward Terpene‐Based Thermosets
White‐light irradiation enables the photoinitiator‐free curing of fully bio‐based terpene epoxy–anhydride systems. A light‐induced switch in epoxide ring‐opening selectivity leads to colorless, transparent thermosets with enhanced thermomechanical performance, revealing an unexpected pathway for sustainable terpene‐based network formation.
Chenxi Zhang +3 more
wiley +2 more sources
Synthetic biolubricant basestocks with improved low temperature and oxidative stability were prepared by chemical modification of epoxidized oleic acid (EOA).
Jumat Salimon, Nadia Salih, Emad Yousif
doaj +1 more source
Catalytic and mechanistic studies into the epoxidation of styrenes using manganese complexes of structurally similar polyamine ligands [PDF]
Two structurally similar polyamine ligands (7 and 8) have been prepared, which differ only by the presence of either a secondary or tertiary nitrogen donor within their N5 donor set.
Watkinson, M +11 more
core +1 more source
Epoxidation and thermal study of vegetable oils in a calorimetric reactor [PDF]
In this work both calorimetric study as well as epoxidation reaction have been carried out using : soybean oil, sunflower oil and rapesedd oil. The main objective of this work is analyze the different behaviour of these oils and compare the results ...
Nocco, Emanuele
core
Enabling Highly (R)-Enantioselective Epoxidation of Styrene by Engineering Unique Non-Natural P450 Peroxygenases [PDF]
Unlike the excellent (S)-enantioselective epoxidation of styrene performed by natural styrene monooxygenase (ee >99%), the (R)-enantioselective epoxidation of styrene has not yet achieved a comparable efficiency using natural or engineered oxidative ...
Zhiqi, Cong +9 more
core +1 more source
Heterogenisation of ketone catalysts within mesoporous supports for asymmetric epoxidation
The synthesis of the first mesoporous silica (150 Å) anchored carbohydrate-derived chiral ketone is described. This new heterogeneous catalyst has been shown to be effective in the asymmetric epoxidation of olefins by oxone.
Robert Raja +5 more
core +1 more source
Resolution pharmacology is an emerging strategy to tackle inflammatory pathologies. Bioinspired meroterpenoids induce a lipid mediator class switch toward inflammation resolution in vitro and in vivo by targeting key nodes in lipid mediator biosynthesis and neutral lipid dynamics.
Lorenz Waltl +20 more
wiley +1 more source
Leucaena Oil Functionalized With Osmium Tetroxide as a Precursor for Polyol‐Based Polyurethane
Leucaena leucocephala seed oil is converted into a hydroxyl‐functional biopolyol through OsO4‐mediated dihydroxylation. The resulting biopolyol shows a hydroxyl number of 160–175 mg KOH g−1 and is successfully used to produce flexible, open‐cell polyurethane foams, highlighting a renewable route for converting underutilized biomass into value‐added ...
Giovanni Miraveti Carriello +13 more
wiley +1 more source
Development and Evaluation of Automotive Lubricating Oil from Jatropha curcas Oil
A Jatropha curcas-based bio-lubricant was developed and evaluated for automotive applications through acid esterification, base-catalyzed transesterification, in-situ peracetic acid epoxidation, and multi-additive blending.
Isaac Nsor +2 more
doaj +1 more source

