Dynamic Potassium Segregation Drives Cu<sup>2+</sup> → Cu<sup>+</sup> Transition and Redefines Alkali-Metal Promotion in Selective Propylene Epoxidation. [PDF]
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Single-carbon insertion enables conversion of cyclopropenes into cyclobutenes: access to oxaspiro[2.3]hexenes. [PDF]
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Structural basis for the carboxylation and epoxidation of human gamma-glutamyl carboxylase. [PDF]
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Ag(111) Remains Significantly Reduced In Situ under Simulated Ethylene Epoxidation Conditions. [PDF]
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Flavin-dependent monooxygenases as versatile biocatalysts in biomanufacturing: mechanisms, engineering, and applications. [PDF]
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Giant viruses encode vitamin K-based redox modules for lipid modification. [PDF]
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Segmented epoxy-based non-isocyanate polyurethanes with thermoreversible Diels-Alder junctions. [PDF]
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Selective hydrogenation of epoxides would be a direct and powerful approach for alcohol synthesis, but it has proven to be elusive. Here, electrochemically epoxide hydrogenation using electrons and protons as reductants is reported. A wide range of primary, secondary, and tertiary alcohols can be achieved through selective Markovnikov or anti ...
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