Results 151 to 160 of about 4,035,607 (255)

Synthesis and One‐Electron Reduction of Donor‐Acceptor‐Stabilized SiII–EII–SiII Trimetallylenes (E = Ge, Sn, Pb)

Angewandte Chemie, EarlyView.
The first isolable trimetallylenes (SiII)2EII (E = Ge, Sn, Pb) with pπ‐type silanylidenyl donors have been synthesized, having donor–acceptor electronic structures that give rise to near‐infrared absorption and enable access to bis(silanylidenyl)‐supported GeI and SnI radical anions upon one‐electron reduction with elemental potassium. ABSTRACT Herein,
Chaopeng Hu, Shenglai Yao, Christian Lorent, Matthias Driess   +3 more
wiley   +2 more sources

Antioxidant Activity of Chlorogenic Acid Evaluated via EPR Spectroscopy and Its Visual Tracking in Mouse Kidney. [PDF]

Nutrients
Quan L, Li C, Shen P, Zhou E, Yin G, Guo X.   +5 more
europepmc   +1 more source

T‐Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond

Angewandte Chemie, EarlyView.
A cationic, structurally constrained stibenium platform mediates anti‐Markovnikov hydrostibination of alkenes via element–ligand cooperativity (ELC), thereby bypassing the need for weak Sb─H bonds. ABSTRACT The hydrostibination of alkenes represents a largely underdeveloped transformation, owing to the intrinsic lability of the required Sb─H reagents ...
Ekta Nag, Lars Ole Busse, Andreas Albers, Manuel Schmitt, Lutz Greb   +4 more
wiley   +2 more sources

Nanomedicine in 2026: Illustrative Quantitative Analyses of EPR Heterogeneity, Clinical Trial Attrition, and Emerging Horizons for Active Nanotherapeutics. [PDF]

Int J Nanomedicine
Fayez SM.
europepmc   +1 more source

Decouple H2O2 Electrosynthesis From Microenvironmental Decomposition via Atomic Site Density Engineering

Angewandte Chemie, EarlyView.
Using defect‐rich Co‐N2O2 single‐atom catalysts as a model system, this work reveals that atomic site density governs the competition between H2O2 electrosynthesis and microenvironmental decomposition during 2e−‐ORR. Optimised site isolation suppresses HPRR and HDR, thereby establishing a site‐density principle to balance H2O2 formation and ...
Junwen Chen, Hongyu Zhou, Qiming Zhang, Shuang Zhong, Wei Ren, Lei Shi, Li Gao, Shaobin Wang, Xiaoguang Duan   +8 more
wiley   +2 more sources

Natural Maghemite Nanoparticles in Crude Oil Seen by Electron Paramagnetic Resonance. [PDF]

ACS Omega
Pessoa MS, Moscon PS, Vicente M, Santos MFP, Flores EMM, Morais PC, Narcizo de Souza PE, Sousa M, Passamani EC.   +8 more
europepmc   +1 more source

CO2 as a Redox Shuttle Enables Photocatalytic Dehydrogenative Decarbonylation of Biomass‐Derived Alcohols to Light Alkanes

Angewandte Chemie, EarlyView.
A heterogeneous photocatalytic system has been developed that enables the dehydrogenative decarbonylation of primary alcohols under visible light using highly dispersed oxidic iron sites supported on aryl‐modified graphitic carbon nitride (Fe@f–gC3N4).
Jun Hu, Wenhao Su, Chaoqin Zeng, Bruno Vinicius Manzolli Rodrigues, Nils Rockstroh, Susanna Monti, Giovanni Barcaro, Piotr Kuśtrowski, Aleksander Jaworski, Jabor Rabeah, Adam Slabon, Shoubhik Das   +11 more
wiley   +2 more sources

Dynamic Covalent Radical Recombination for the Assembly of Tuneable Responsive Porous Organic Cages. [PDF]

Angew Chem Int Ed Engl
Hartmann Y, Oestreich R, Wada Y, de Bary P, Kawano M, Janiak C, Schmidt BM.   +6 more
europepmc   +1 more source

Crystallise, poise, capture: a multimodal platform for correlated structural and spectroscopic characterisation of redox enzymes. [PDF]

J Biol Inorg Chem
Laxmi S, Jaho S, Myers WK, Vincent KA, Carr SB.   +4 more
europepmc   +1 more source

Engineering BN‐Doped Open‐Shell Polycyclic Hydrocarbons for Enhanced Photothermal Conversion and Therapy

Angewandte Chemie, EarlyView.
Two novel bonded BN‐doped polycyclic hydrocarbons BN‐Dira and BN‐Tetra with open‐shell character were rationally designed and synthesized. Their molecular structures were unambiguously confirmed by crystallographic analysis. Facilitated by their intense absorption in the NIR region, high PCE (83.6%) and good photothermal stability, BN‐Dira and BN‐Tetra
Peiyun Zeng, Ziqi Zhuang, Huan Luo, Yubin Fu, Peiyu Wang, Yating Zheng, Gang Liu, Junzhi Liu   +7 more
wiley   +2 more sources