Results 81 to 90 of about 313,235 (301)

Thermodynamic and Quantum Thermodynamic Analyses of Brownian Movement [PDF]

open access: yesarXiv, 2006
Thermodynamic and quantum thermodynamic analyses of Brownian movement of a solvent and a colloid passing through neutral thermodynamic equilibrium states only. It is shown that Brownian motors and E. coli do not represent Brownian movement.
arxiv  

In Situ Constructed Magnetic Core‐Shell Hydrogen‐Bonded Organic Framework‐on‐Metal–Organic Framework Structure: an Efficient Catalyst for Peroxymonosulfate Activation

open access: yesAdvanced Functional Materials, EarlyView.
In this work, a magnetic core‐shell catalyst (HOF‐on‐Fe3O4/ZIF‐67) is successfully synthesized, consisting of a metal–organic framework (ZIF‐67) with magnetic Fe3O4 as the core and a porous hydrogen‐bonded organic framework (HOF) as the shell. The catalyst efficiently activated peroxymonosulfate, resulting in rapid and effective removal of water ...
Yingying Du   +4 more
wiley   +1 more source

Thermodynamics for non-equilibrium pattern formation

open access: yesAIP Advances, 2011
The second entropy theory for non-equilibrium thermodynamics is used to show that the optimum structure or pattern of a time-dependent system corresponds to the maximum entropy. A formula for the total entropy of convective heat flow is derived.
Phil Attard
doaj   +1 more source

Thermal Contact

open access: yesEntropy, 2008
The concepts of temperature and entropy as applied in equilibrium thermodynamics do not easily generalize to nonequilibrium systems and there are transient systems where thermodynamics cannot apply.
Tony Chung   +2 more
doaj   +1 more source

Recent Advances in Single‐Atom Catalyst for Solar Energy Conversion: A Comprehensive Review and Future Outlook

open access: yesAdvanced Functional Materials, EarlyView.
This review highlights the potential of single‐atom catalysts in three key photocatalytic reactions: the hydrogen evolution reaction (HER), nitrogen reduction reaction for ammonia synthesis, and carbon dioxide reduction reaction (CO2RR) for chemical fuels.
Saad Mehmood   +5 more
wiley   +1 more source

New formulation of local-equilibrium thermodynamics

open access: yesAIP Advances, 2019
This study points out that the conventional separation of balance equations for energy in fluids into a flow and a source term is not thermodynamically valid.
Nobuo Yoshida
doaj   +1 more source

Chemical Equilibrium as Balance of the Thermodynamic Forces [PDF]

open access: yesarXiv, 2004
The article sets forth comprehensive basics of thermodynamics of chemical equilibrium as balance of the thermodynamic forces. Based on the linear equations of irreversible thermodynamics, De Donder definition of the thermodynamic force, and Le Chatelier's principle, new thermodynamics of chemical equilibrium offers an explicit account for multiple ...
arxiv  

Electroplating of Wear‐ and Corrosion‐Resistant CrCoNi Medium‐Entropy Alloys beyond Hard Chromium Coatings

open access: yesAdvanced Functional Materials, EarlyView.
The electroplating of a CrCoNi medium‐entropy alloy is achieved using a mixture of an ionic liquid and an aqueous solution containing metal salts. The CrCoNi medium‐entropy alloy thin film exhibits high wear and corrosion resistance superior to conventional hard chromium coatings. Abstract High‐entropy alloys (HEAs) and medium‐entropy alloys (MEAs) are
Yuki Murakami   +7 more
wiley   +1 more source

Non-Equilibrium Thermodynamics formalism for Marcus cross-exchange electron transfer reaction rates [PDF]

open access: yesarXiv, 2007
The cross-exchange electron transfer expression arising from Marcus theory is deduced using Onsager's non-equilibrium Thermodynamics formalism.
arxiv  

Transient Current Responses of Organic Electrochemical Transistors: Evaluating Ion Diffusion, Chemical Capacitance, and Series Elements

open access: yesAdvanced Functional Materials, EarlyView.
This work establishes a general theory of the current transient of ionic‐electronic transistors under a step of gate voltage. The dominant effect is a transient charging of the channel by diffusion of ions. The additional influence of electrolyte capacitance and resistance splits the fundamental time constant of diffusion into two different components.
Juan Bisquert, Nir Tessler
wiley   +1 more source

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