Results 141 to 150 of about 3,981 (217)

Photoinduced Electron Transfer (PET) as Key to Accelerate the Cycloreversion Reaction of Arylquadricyclanes

open access: yesChemistry – A European Journal, EarlyView.
It is demonstrated that the photoinduced cycloreversion of a methoxynaphthylquadricyclane in the presence of suitable photocatalysts gives quantitatively the corresponding norbornadiene. As this photochromic norbornadiene‐quadricyclane cycle has favorable properties for light energy conversion, this method provides a useful tool for the targeted ...
Julian Felix Maria Hebborn   +4 more
wiley   +1 more source

Diffusion of Carbamazepine in Hydrophobic Zeolites: A Comparative Study Using Classical and Machine‐Learned Potentials

open access: yesChemistry – A European Journal, EarlyView.
Can hydrophobic, shape‐selective zeolites efficiently remove the persistent pharmaceutical CBZ from water? This work moves beyond the static picture of interaction energies by modeling diffusion with umbrella sampling and machine‐learned potentials. Even high intrinsic diffusion barriers can be overcome through exergonic adsorption from water, yielding
Jakob Brauer   +4 more
wiley   +1 more source

Semiconducting Single‐Wall Antimony Oxide Nanotubes and Oxidotritelluridoantimonate(V) Anions

open access: yesChemistry – A European Journal, EarlyView.
Antimony(V) binds directly to tellurium(−II) in the (SbOTe3)3− anion. The latter has been found between Sb2O3 nanotubes in a microporous cetineite structure. The Sb2O3 nanotube is positively polarized on its outer surface and negatively polarized on its inner surface, corresponding to a cylindrical capacitor. Substantial charge transfer from the anions
Huanyu He   +3 more
wiley   +1 more source

Flipping the Card With Enantiodivergent Organocatalysis

open access: yesChemistry – A European Journal, EarlyView.
This minireview elaborates on recent organocatalytic strategies for achieving enantiodivergence—the ability to access both product enantiomers using a single chiral catalyst. It highlights how achiral stimuli, such as solvent polarity and chemical additives, along with minimal catalyst modifications, trigger stereochemical inversions in reactions ...
Debora Iapadre   +3 more
wiley   +1 more source

Covalent Insertion of a Mn(Salen) Type Complex in Cross‐Linked Protein Crystals: Design of an Enantioselective Artificial Epoxidase

open access: yesChemistry – A European Journal, EarlyView.
An Artificial metalloenzyme was designed by a Michael addition between a MnSalen complex and a cysteine residue within NikA crystals. The heterogeneous catalyst was found capable of an enantioselective and stereospecific epoxidation of cis‐β‐methylstyrene in cristallo.
Manel Boukhallat   +8 more
wiley   +1 more source

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