Results 181 to 190 of about 1,308 (261)

Catalytic Enantioselective Intramolecular Aza‐Michael Addition to α,β‐Unsaturated Esters

open access: yesAngewandte Chemie, EarlyView.
A general method for accessing enantioenriched saturated N‐heterocycles via a catalytic enantioselective intramolecular aza‐Michael reaction to α,β‐unsaturated esters is described. A superbasic bifunctional iminophosphorane (BIMP) catalyst was key to enabling reactivity of the high pKa sulfonamide pronucleophile, whilst delivering good to excellent ...
Evan G. W. Rutter   +5 more
wiley   +2 more sources

Modeling Wildfire Effects on Ecosystem Services in two Disparate California Watersheds and Communities. [PDF]

open access: yesEnviron Manage
Busari I   +5 more
europepmc   +1 more source

Molecular Detection and Clinical Impact of <i>Helicobacter pylori</i> Virulence Genes in Gastric Diseases: A Study in Arequipa, Peru. [PDF]

open access: yesBiomedicines
Ita-Balta Y   +7 more
europepmc   +1 more source

A Ruthenium‐(Ph‐BPE) Catalyst for Asymmetric Alkynylation of Fluoral: Enantioselection From 1 of 12 Fluxional Stereogenic‐at‐Ruthenium Complexes

open access: yesAngewandte Chemie International Edition, EarlyView.
The first enantioselective alkynylations of aqueous fluoral are described. These processes are catalyzed by an iodide‐bound ruthenium‐(Ph‐BPE)‐catalyst; an octahedral metal complex that can exist as 12 diastereomeric‐at‐metal isomers. Calculations reveal that 2 of 12 stereoisomeric complexes account for 99.9% of the Boltzmann population and that ...
Weijia Shen   +6 more
wiley   +1 more source

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