Results 161 to 170 of about 63,836 (241)

Decorating Carbon Nitride via the Integration of Phosphorylation with Carbon Self‐doping toward Enhanced Photocatalytic Hydrogen Evolution

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The electron transfer from the grafted ATMP to the adjacent heptazine ring can induce the proton transfer of the hydroxyls on ATMP to Pt co‐catalyst nanoparticles. This coupling of proton transfer and electron transport also promotes the separation and transport of charge carriers and therefore advances the performance of photocatalytic hydrogen ...
Yike Li   +5 more
wiley   +1 more source

Molecularly Engineered Dual‐Crosslinked Polymer Dielectrics for 200 °C Capacitive Energy Storage

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This work establishes a molecular engineering strategy that constructs a robust dual‐crosslinked network in polymer nanocomposites, achieving a record‐high energy density of 5.17 J cm−3 with >90% efficiency at 200 °C. The multiscale‐validated design simultaneously enhances dielectric polarization and introduces deep electron traps, resulting in ...
Xue Li   +9 more
wiley   +1 more source

d‐Orbital Electron Spin Polarization Field Inhibits Photo‐Generated Carrier Recombination for Panel Photoelectrocatalysis

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A solution‐processable sub‐nanocrystal of metal coordinated conjugated reticular oligomer with spin polarization functionality is employed as an active layer in planar photoelectrochemical water splitting. The rapid recombination of photo‐generated carriers remains a critical challenge limiting the photo‐electrocatalytic water splitting performance in ...
Ruijuan Zhang   +6 more
wiley   +1 more source

Precisely Constructed Asymmetric Coordination Tuned High‐Spin Co Sites for Sacrificial Agent‐Free H2O2 Photocatalytic Production

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The asymmetric Co–N2O2 coordination structure was precisely constructed through the assembly of Salen COF. The high‐spin (t2g4eg3$$ {\mathrm{t}}_{2\mathrm{g}}^4{\mathrm{e}}_{\mathrm{g}}^3 $$) Co center enables Pauling‐type O2 adsorption, inhibiting the cleavage of the O–O bond. π‐d conjugation enhances charge separation and transport.
Wenhui Qi   +5 more
wiley   +1 more source

A Co‐Self‐Assembled Monolayer With Enhanced Coverage and Defect Passivation for Efficient Inverted Perovskite Solar Cells

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This study achieved a co‐self‐assembled monolayer (Co‐SAM) with more uniform coverage on nickel oxide substrates and enhanced passivation of buried interfaces by incorporating 4PABCz into Me‐4PACz. Perovskite solar cells fabricated with this Co‐SAM achieved an efficiency of 26.33% and exhibited enhanced stability. The combination of nickel oxide (NiOx)
Zhiwei Deng   +16 more
wiley   +1 more source

Managing Crystallization in Tin‐Lead Perovskite Solar Cells via Differential Chelating Coordination

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A chelation‐mediated crystallization strategy is developed for Sn–Pb perovskites using 1,10‐phenanthroline. Stronger coordination with Sn than Pb helps reconcile their mismatched crystallization behavior, leading to improved crystalline quality, fewer defects, and reduced oxidation.
Zihao Feng   +9 more
wiley   +1 more source

Integrated Solvent‐Catalyst‐Dopant Strategy via Acidic DES for Synthesizing Lignin‐Derived Carbon Dots With High‐Quantum Yield to Achieve Efficient Photocatalytic Degradation of Tetracycline

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A deep eutectic solvent (ChCl/pTSA) platform enables integrated solvent, catalyst, and dopant functions, producing sulfur‐doped carbon quantum dots with a high sp2‐C content (82.8%) and a quantum yield of 56.9%. When combined with TiO2, the CQDs form TiOC and TiOS interfacial bridges, achieving 97.3% tetracycline photodegradation with excellent ...
Xinhang Li   +4 more
wiley   +1 more source

SPARCL1 and NT‐proBNP as biomarkers of right ventricular‐to‐pulmonary artery uncoupling in pulmonary hypertension

open access: yesESC Heart Failure, Volume 12, Issue 2, Page 1416-1426, April 2025.
Abstract Aims SPARCL1 was recently identified as a biomarker of right ventricular (RV) maladaptation in patients with pulmonary hypertension (PH), and N‐terminal pro‐brain natriuretic protein (NT‐proBNP) is an established biomarker of RV failure in PH. The present study investigated whether NT‐proBNP and SPARCL1 concentrations are associated with load ...
Oliver Dörr   +15 more
wiley   +1 more source

Iminodirhodium‐ and Iminocopper‐Catalyzed CH Activation: Chemoselective Oxidation of Alcohols and Aldehydes via Intermolecular Hydride Abstraction

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Chemoselective hydride abstractor iminometalloids, derived from O‐mesylacetoxime (MAO) using Rh2(II/II) or Cu(I) catalysts, can activate the C–Hα bonds of alcohols and aldehydes ultimately forming ketones, carboxylic acids, and esters even in the presence of C–H bonds with comparable bond strengths.
Raghunath Reddy Anugu   +2 more
wiley   +1 more source

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