Half-Titanocenes Bearing Unsymmetric Imidazolin-2-iminato Ligand that Exhibits Efficient Cyclic Olefin Incorporation in Ethylene Copolymerization. [PDF]
Jantawan K +5 more
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Nanozymes (NZs) have emerged as versatile artificial enzymes with tunable catalytic properties driven by atomic coordination, defect engineering, and surface chemistry. This review presents a bio–nano interface framework linking synthesis strategies, structural design, and catalytic behavior within complex biological microenvironments.
Karen Guadalupe Quintero‐Garrido +6 more
wiley +1 more source
Photoredox-controlled alternating copolymerization enables highly crystalline structures and block copolymers from thermoplastic to elastomer. [PDF]
Xu M +5 more
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Bisphenol A-responsive microgel comprising hydrophilic poly(acrylamide) network. [PDF]
Kawamura A +3 more
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Controlled Chain-Walking Polymerization in the Gas Phase to Ultrahigh Molecular Weight Polyethylene. [PDF]
Wang Y, Li S, Zhang M, Dai S.
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Structural Dispersity as a Determinant of Li-Ion Transport in Ethylene-Oxide-Based Graft Polymer Electrolytes. [PDF]
Vigolo A +7 more
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Dual-Pathway Strategy for Click-Type Functionalization and Programmable Polymer Deconstruction. [PDF]
Levkovsky IO +3 more
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Amine Tris(phenolate) Ligands as a Versatile Scaffold for Early and Late Transition Metals: Synthesis and Application. [PDF]
Kumari N +5 more
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Visualization of on-surface ethylene polymerization through ethylene insertion
Science, 2022Polyethylene production through catalytic ethylene polymerization is one of the most common processes in the chemical industry. The popular Cossee-Arlman mechanism hypothesizes that the ethylene be directly inserted into the metal–carbon bond during chain growth, which has been awaiting microscopic and spatiotemporal experimental ...
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Pressure-Induced Polymerization in Solid Ethylene
The Journal of Physical Chemistry B, 2005Ethylene is the simplest organic molecule containing a double bond and is the starting monomeric unit in the synthesis of polyethylene, one of the most largely produced polymers. Here we report a high pressure infrared study of ethylene at room temperature.
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