Weakly Coordinated Solvent Network-Induced Ternary Water-Deficient Eutectic Electrolytes for Low-Polarization Zn Anodes. [PDF]
Adv Sci (Weinh)A water‐deficient ternary eutectic electrolyte employs weakly coordinating solvents to decouple strong solvation interactions, constructing a loose and dynamic solvation network. This optimized solvation structure accelerates Zn2+ transport and interfacial kinetics, promotes robust SEI formation, and ultimately enables highly stable and reversible Zn ...
Li Q +7 more
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To Be or Not to Be Eutectic: Anomalous Glass Forming Ability Governed by Melt Structural Complexity. [PDF]
Adv Sci (Weinh)Challenging the eutectic rule, congruently melting Ti–Cu alloys show greater glass‐forming ability than their eutectic counterparts. This arises from the congruent melt's structural complexity: higher cluster diversity and stronger inter‐cluster correlations from entropy–enthalpy competition.
Chen W +18 more
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Anion-Driven Surface Reconstruction Enables Direct Regeneration of LiCoO<sub>2</sub> Cathode Material. [PDF]
Adv Sci (Weinh)The anion scpecies in molten salt systems critically govern the surface reconstruction of regenerated LiCoO2. LiOH−LiCl flux, featuring strong Cl− adsorption and facile dissociation, directs preferential relithiation on (003) facets and forms a Li−O enriched interface.
Zheng M, Qian S, Li M, Zhang S, Lu J.
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Physical Review Letters, 1994 A full phase field model of eutectic growth is proposed, which incorporates the generic features of a eutectic phase diagram and reduces to the sharp-interface model in the appropriate limit. Large scale two-dimensional simulations are presented for the isothermal solidification of a uniformly undercooled eutectic melt, in which the Avrami exponent is ...
Elder, K. R. +3 more
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New approaches to casting hypereutectic Al-Si alloys to achieve simultaneous refinement of primary silicon and modification of eutectic silicon [PDF]
, 2013 This thesis was submitted for the degree of Doctor of Philosophy and awarded by Brunel UniversityHypereutectic Al-Si alloys are of increasing interest for applications that require a combination of light weight and high wear resistance, such as pistons ...
Al-Helal, Kawther
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Chiral Solvent Discovery: Exploring Chiral Eutectic Mixtures and Deep Eutectic Solvents [PDF]
, 2022 Deep eutectic solvents (DES) are mixtures that have a melting point much lower than any of the components. Because the properties of a DES, such as chiral discrimination, can be controlled through choice of components, DES have potential as solvents in ...
Paola, Ariza +10 more
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Solidification behavior and microstructural evolution of near-eutectic Zn-Al alloys under intensive shear [PDF]
, 2008 Copyright @ 2009 ASM International. This paper was published in Metallurgical and Materials Transactions A, 40(1), 185 - 195 and is made available as an electronic reprint with the permission of ASM International.
Ji, S, S. Ji, Z. Fan, Fan, Z
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The application of deep eutectic solvent ionic liquids for environmentally-friendly dissolution and recovery of precious metals [PDF]
, 2016 publisher: Elsevier articletitle: The application of deep eutectic solvent ionic liquids for environmentally-friendly dissolution and recovery of precious metals journaltitle: Minerals Engineering articlelink: http://dx.doi.org/10.1016/j.mineng.2015.09 ...
Harris, RC +8 more
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Exploring Eutectic Mixing of Quinones for Engineering High Energy-Density Electrolytes [PDF]
, 2023 Eutectic electrolytes can attain high concentrations of redox-active species, offering a path towards high energy density redox flow batteries. Here we introduce a new entropically-driven eutectic mixing approach using organic small molecules.
Devi, Ganapathi +7 more
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Presolidification in Eutectic Droplets
Physical Review Letters, 2023 Evidence of presolidification, the counterpart to premelting, is reported. Near the eutectic temperature, T_{C}, the propagation direction of thermal gradient driven motion of eutectic Ge-Pt droplets on Ge(110) is determined by presolidification.
Bene Poelsema +3 more
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