Results 111 to 120 of about 488,344 (296)

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

Chemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz, Sven Schaefer, Oksana Storcheva, Gabriele Raudaschl‐Sieber, Johannes Bitzer, Wolfgang Kleist, Klaus Köhler   +6 more
wiley   +1 more source

Compositional Stages in the Thermal Activation of Metal‐Organic Frameworks in Vacuo: In Situ Spectroscopy and Computation

Chemistry – A European Journal, EarlyView.
The ultrahigh surface area intrinsic to many metal‐organic frameworks (MOFs) may only be accessed after the removal of synthesis solvent from within the pores. This study elucidates the electronic and structural changes undergone through the guest removal process within a commonly used CUS MOF.
George W. Fritze, John W. Robinson, Adam J. Matzger   +2 more
wiley   +1 more source

Development of a Mechanically Regenerating Desublimator for Freeze‐Drying Systems in the Food Industry

Chemie Ingenieur Technik, EarlyView.
Thermal defrosting limits desublimator efficiency in freeze‐drying. This review and case study compares thermal versus mechanical regeneration, links frost properties and external heat transfer to energy demand, and summarizes pilot‐scale scraping results enabling single‐unit, continuous lyophilization.
Moritz Krummenacher, Mirko Kleingries, Edgar Zimmer, Roman Blättler   +3 more
wiley   +1 more source

Zebrafish ventral gastrula fate map reveals neural crest progenitor domain

Developmental Dynamics, EarlyView.
Abstract Background Fate maps relate progenitor cell positions to later fates and locations of their progeny, revealing early embryonic organization. Previous zebrafish fate maps identified the origin of germ layers and derivative cell fates, but ventral gastrula progenitor domains were not fully resolved. In particular, the neural crest, a multipotent
Elaine E. Kushkowski, Victoria E. Prince
wiley   +1 more source

Niobium‐Based Chalcogenides as Emerging Electrode Materials for Rechargeable Batteries

EcoEnergy, EarlyView.
This review highlights recent advances in Nb‐based TMCs, covering their structure‐property relationships, synthesis strategies, electrochemical mechanisms, and energy‐storage applications. Emerging approaches including defect engineering, operando characterization, DFT modeling, and AI‐assisted design are discussed to accelerate the development of high‐
Narasimharao Kitchamsetti, Ana L. F. de Barros, Sungwook Mhin, HyukSu Han   +3 more
wiley   +1 more source

One‐Step Synthesis of Si–Graphene Heterostructures via in‐Flight Gas‐Phase Mixing for High‐Capacity Silicon‐Rich Anodes

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A one‐step gas‐phase synthesis directly assembles amorphous Si nanoparticles with few‐layer graphene heterostructures via in‐flight mixing. Compositions with only 15 wt.% FLG deliver ~2800 mAh g−1 (Si + FLG) at 0.05 C and retain ~1400 mAh g−1 after 100 cycles at a high cycling rate of 1 C, enabled by a percolated, strain‐buffering graphene network that
Muhammad Ali, Mukarram Ali, Yasaman Jarrahizadeh, Axel Lorke, Michael A. Pope, Hartmut Wiggers   +5 more
wiley   +1 more source

Numerical investigation of direct absorption evacuated tube solar collector using alumina nanofluid

Journal of Thermal Engineering
Direct absorption evacuated tube solar collectors are a new type of collector that has great potential to use in a solar system. In the present work, energy analysis of the direct absorption evacuated tube solar collectors employing Al2O3 nanoparticles ...
Niloofar SHAHINI
doaj   +1 more source

Enhanced Ionic Conductivity and Moisture Stability of Zr‐Based Halide Solid Electrolytes via Ta5+ Doping for All‐Solid‐State Batteries

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The high‐valence Ta5+‐substituted LZC (LZT0.3C) demonstrates high ionic conductivity, excellent compressibility, and impressive moisture stability, contributing to the long‐term cycling durability of ASSLBs. Recently developed halide solid‐state electrolytes (SSEs) have become promising alternatives for the next generation inorganic SSEs, primarily due
Jin Hu, Yuhan Ma, Yihao Cheng, Chunsheng Shi, Biao Chen, Liying Ma, Jianli Kang, Fang He, Naiqin Zhao, Chunnian He   +9 more
wiley   +1 more source

Smart optimization of a thermosyphon heat pipe for an evacuated tube solar collector using response surface methodology (RSM)

, 2019
Smart optimization of a thermosyphon heat pipe for an evacuated tube solar collector using response surface methodology ...
Z Tian (7732379), M Bakouri (13496011), MM Sarafraz (14454861), I Tlili (13489486), MR Safaei (15829916)   +4 more
core  

Rapid Joule‐Heating‐Induced Non‐Equilibrium Exsolution in Perovskite Oxides for Enhanced Photothermal CO2 Methanation

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Rapid Joule heating induces Ni—Fe exsolution from perovskite oxides, forming Ni–Fe/oxide heterointerfaces that enhance photothermal CO2 methanation activity and selectivity. Achieving selective CO2 methanation under photothermal conditions requires catalysts capable of maintaining non‐equilibrium interfacial states that balance reduction and oxidation ...
Qiankai Zhang, Qinghao Li, Kaiyue Xing, Gan Jin, Lei Fu, Le Shi, Yang Wang, Junbo Wang, Kai Wu, Jun Zhou   +9 more
wiley   +1 more source