Results 101 to 110 of about 44,774 (227)

Hyperspectral full-field quick-EXAFS imaging at the ROCK beamline for monitoring micrometre-sized heterogeneity of functional materials under process conditions

open access: yesJournal of Synchrotron Radiation
Full-field transmission X-ray microscopy has been recently implemented at the hard X-ray ROCK–SOLEIL quick-EXAFS beamline, adding micrometre spatial resolution to the second time resolution characterizing the beamline.
Valérie Briois   +11 more
doaj   +1 more source

Inter‐Atomic Synergy on Single‐Atom Alloy Promotes Cyclohexanone Oxime Electrosynthesis

open access: yesAdvanced Materials, EarlyView.
Electrosynthesis of cyclohexanone oxime using renewable electricity offers a greener alternative to traditional energy‐intensive methods. Here, we develop a Fe1Bi single‐atom alloy that delivers 70.9% Faradaic efficiency and 0.94 mmol cm−2 h−1 yield rate through the atomic‐scale synergistic mechanism.
Panlong Zhai   +10 more
wiley   +1 more source

Electron‐Induced Molecular Programming Drives Interfacial Chemistry for Ah‐Level Zinc Batteries

open access: yesAdvanced Materials, EarlyView.
We establish an electron‐driven molecular programming strategy that converts spontaneous solid electrolyte interphase formation into a bonding‐defined interfacial architecture. Coordinative integration of p‐bromoaniline with ZnF2 forms a dipole‐regulated molecular lock that reconfigures interfacial electrostatics, suppresses parasitic water reactions ...
Feifei Wang   +12 more
wiley   +1 more source

Undercoordinated Molybdenum Catalysts Enable Ultrafast Quasi‐Solid Sulfur Chemistry in Sodium‐Sulfur Batteries

open access: yesAdvanced Materials, EarlyView.
An unsaturated coordination chemistry strategy activates a quasi‐solid‐state redox pathway by strengthening NaPSs adsorption and accelerating redox conversion kinetics, thereby overcoming the kinetic bottlenecks that limit high‐rate performance. In situ transmission electron microscopy, combined with newly developed Na‐ion diffusion descriptors ...
Mingyue Wang   +12 more
wiley   +1 more source

Powder‐to‐Film Conversion of Nickel Single‐Atom Catalysts into Binder‐Free and Resistant Electrodes

open access: yesAdvanced Materials Interfaces, EarlyView.
A reproducible strategy is reported for fabricating standalone thin‐film electrodes composed of CNx‐supported Ni single‐atom catalysts. The resulting binder‐free electrodes exhibit robust stability, enhanced charge transfer, and superior electrochemical performance, offering scalable opportunities for applications in electrochemistry. ABSTRACT Although
Milla Vigliengo   +8 more
wiley   +1 more source

GNXAS: A SOFTWARE PACKAGE FOR ADVANCED EXAFS MULTIPLE-SCATTERING CALCULATIONS AND DATA-ANALYSIS

open access: yesTASK Quarterly, 2000
Computational and theoretical advances for the interpretation of the x-ray absorption spectroscopy (XAS) cross-section, and associated extended x-ray absorption file structure (EXAFS), originally published in Phys. Rev.
ADRIANO FILIPPONI, ANDREA DI CICCO
doaj  

Amido‐Amine Co(II) Precursor‐Based Atomic/Molecular Layer Deposition Processes for Cobalt‐Organic Thin Films and Their Thermal Conversion to CoO Thin Films

open access: yesAdvanced Materials Technologies, EarlyView.
Three new atomic/molecular layer deposition processes are developed for Co‐organic thin films using a promising all‐nitrogen‐coordinated cobalt precursor. The study examines film growth, reaction mechanisms, chemical stability, and decomposition pathways of the resulting films through extensive characterization techniques and DFT calculations ...
Topias Jussila   +9 more
wiley   +1 more source

Two-metal-edge extended X-ray absorption fine structure analysis of oxygen octahedral rotation in SrTiO3 using the reverse Monte Carlo method

open access: yesJournal of Synchrotron Radiation
A three-dimensional analysis method for X-ray absorption spectra, combining two-metal-edge extended X-ray absorption fine structure (EXAFS) analysis with reverse Monte Carlo simulations, was applied to study the cubic-to-tetragonal phase transition in ...
Kai Kamijo   +3 more
doaj   +1 more source

MOx/Rh Metallene with Energetic Interfaces as Efficient Bifunctional Electrocatalyst for Durable Water Splitting

open access: yesAdvanced Science, EarlyView.
 . ABSTRACT Developing excellent activity and stability bifunctional electrocatalysts for alkaline water splitting remains challenging. This work constructs ultrathin MOx/Rh metallene heterostructures (M = Fe, Co, Ni) via atmosphere‐controlled solvothermal synthesis, achieving uniform MOx nanoclusters on Rh metallene with optimized interfaces. The FeOx/
Ruilong Wei   +10 more
wiley   +1 more source

Stabilization of Single Metal Atoms on Graphitic Carbon Nitride: Synthetic Strategies and Emerging Applications

open access: yesAdvanced Science, EarlyView.
This review highlights recent advancements in stabilizing single metal atoms on graphitic carbon nitride emphasizing innovative synthesis strategies and emerging applications in electrocatalysis, photocatalysis and organic transformations, along with key challenges and future perspective. Abstract Emerging as a new frontier in catalysis science, single‐
Wenyao Zhang   +6 more
wiley   +1 more source

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