Results 161 to 170 of about 44,774 (227)

Speciation, Structural Refinement, and Distribution of Ti Sites in Titanium Silicalite‐1 From 47/49Ti NMR Crystallography at 28.2 Tesla

Angewandte Chemie, EarlyView.
Titanium silicalite‐1 (TS‐1), used in industrial selective oxidation processes, depends on specific, yet still unresolved Ti sites, dispersed within the framework of an MFI‐zeolite. Applying high field (28.2 T) 47/49Ti NMR and 17O NMR spectroscopy for an array of TS‐1 catalysts enables the development of an NMR crystallography protocol and the ...
Christoph J. Kaul, Jonas Koppe, Lukas Lätsch, Michael Wörle, Sadig Aghazada, Jacob B. Holmes, Christina Wartmann, Mingji Zheng, Albrecht Berkessel, Trees De Baerdemaeker, Andrei‐Nicolae Parvulescu, Karsten Seidel, J. Henrique Teles, Alexander V. Yakimov, Christophe Copéret   +14 more
wiley   +2 more sources

Mapping the Hierarchical Environmental Transformations of Nanoscale UiO-66 Metal-organic Framework. [PDF]

Environ Sci Technol
Chakraborty S, Mikulska I, Dhumal P, Langford N, Nehzati S, Boseley R, Pham S, Pfrang C, Kaur M, Valsami-Jones E, Ignatyev K, Menon D, Misra SK, Lynch I.   +13 more
europepmc   +1 more source

Selective Electrolysis of Water Under Artificial Seawater Conditions Using Transition Metal Borate Anodes

Advanced Energy Materials, EarlyView.
The borate‐based cobalt‐iron catalyst promotes selective oxidation of water rather than chlorine evolution reaction during electrolysis of seawater. When integrated into a zero‐gap electrolyzer prototype, this catalyst supports robust splitting of artificial seawater into oxygen and hydrogen on an extended timescale.
Ananta R. Fareza, Hank Garg, Luis Miguel Azofra, Darcy Simondson, Tam D. Nguyen, Mohamed R. Rizk, Khang N. Dinh, Rosalie K. Hocking, Douglas R. MacFarlane, Hoang‐Long Du, Alexandr N. Simonov   +10 more
wiley   +1 more source

Catalysis AI Agent Guides Discovering the Universal Design Principle of Cu‐Based Single‐Atom Alloy Catalysts for CO2 Electroreduction

Angewandte Chemie, EarlyView.
Artificial intelligence (AI) enables the systematic analysis and comparative evaluation of experimental and theoretical data, optimizes the catalytic reaction research workflow, and accelerates the discovery of high‐performance electrocatalysts. ABSTRACT Copper (Cu)‐based single‐atom alloys (SAAs) represent a promising strategy for optimizing the ...
Xuning Wang, Zhong Li, Di Zhang, Hao Li, Haoxiang Xu, Daojian Cheng   +5 more
wiley   +2 more sources

Hypercarbon-Centered Gold(I)-Copper(I) Clusters Exhibiting a Dissolution/Crystallization-Induced Photoluminochromism. [PDF]

Chemistry
Lei Z, Zhao P, Kikkawa S, Pei XL, Liu WT, Ube H, Yamazoe S, Ehara M, Shionoya M.   +8 more
europepmc   +1 more source

CO Spillover‐Induced Directed C─C Coupling for CO2 Electroreduction to Multicarbon Products

Advanced Energy Materials, EarlyView.
Efficient CO2 electroreduction to C2+ is achieved by engineering Cu@Ag interfaces, which enhance interfacial CO spillover from Ag to Cu, enrich *CO coverage, and accelerate C─C coupling. A quantitative relationship between CO spillover rate and C2+ activity is also established, defining spillover as a measurable descriptor and advancing rational ...
Yue Guo, Zhaolong Wang, Huiyan Zeng, Jonathan Kong, Xiaojie She, Xingwang Zhu, Shu Ping Lau   +6 more
wiley   +1 more source

Chloride-induced easier phase transformation and catalytic synergy for enhanced seawater splitting. [PDF]

Chem Sci
Ma H, Jin Y, Zhou X, Cui Y, Zhao Y, Chang CY, Yeh MH, Huang WH, Song E, Ma J, Cheng H.   +10 more
europepmc   +1 more source

Deciphering Intricacies in Directional CO2 Conversion From Electrolysis to CO2 Batteries

Advanced Energy Materials, EarlyView.
This review will delve into the inherent connections and distinctions of CO2‐directed conversion in ECO2RR and CO2 batteries, in terms of product types, catalyst selection, catalytic mechanisms, and electrochemical performances, while proposing a benchmarking framework for the evaluation of CO2 batteries and innovative CO2 battery configurations for ...
Changfan Xu, Huaping Zhao, Lizhuang Chen, Weidong Shi, Guosheng Shao, Yong Lei   +5 more
wiley   +1 more source

On the Structure and Redox Behavior of Ni and Cu Single Atoms Supported on Carbon Nitride

Angewandte Chemie, EarlyView.
Magnetic and electronic spectroscopies, combined with DFT, establish the MN4 binding site of Ni and Cu single atoms on carbon nitride and elucidate their redox photochemistry. Ni undergoes geometry‐preserving, reversible M2+/M+ cycling, whereas Cu collapses to an irreversible low‐coordinate Cu+ state, suppressing photocatalysis.
Giovanni Colonnello, Ksenija Maver, Arianna Actis, Gaia Grando, Giacomo Filippini, Tiziano Montini, Michele Melchionna, Paolo Fornasiero, Lucia Nasi, Iztok Arčon, Lorenzo Donà, Bartolomeo Civalleri, Enrico Salvadori, Mario Chiesa   +13 more
wiley   +2 more sources

In Situ X-ray Absorption Fine Structure Spectroscopy Measurement of Suspended Cobalt Oxide Nanoparticle Water Oxidation Catalyst. [PDF]

J Phys Chem Lett
Okazaki M, Goo ZL, Yamamoto H, Yamamoto I, Ikegami K, Tarutani N, Takeiri F, Watanabe T, Nozawa S, Katagiri K, Sugimoto K, Maeda K.   +11 more
europepmc   +1 more source