Results 221 to 230 of about 23,193 (311)

Wrinkled Strain‐Enriched High‐Entropy Metallene Enables Cross‐Site Tandem Nitrate‐to‐Ammonia

open access: yesAngewandte Chemie, EarlyView.
A wrinkled 2D PdFeCoNiCuIn high‐entropy metallene overcomes the low atom utilization of high‐entropy alloys. Indium‐induced strain and p‐d hybridization enable a cross‐site tandem pathway for nitrate reduction to ammonia. It achieves 99.3% Faradaic efficiency and an NH3 yield rate of 4.55 mmol h−1 mgcat−1.
Tianfang Yang   +6 more
wiley   +1 more source

Pressure-Driven Helium Insertion for Structural Stability of CH<sub>3</sub>NH<sub>3</sub>PbBr<sub>3</sub> Hybrid Perovskites. [PDF]

open access: yesChem Mater
Weadock NJ   +10 more
europepmc   +1 more source

Single‐Atom Iron‐Catalyzed Oxidative Esterification: From Methylarenes to the Upcycling of Polystyrene and Lignin‐Derived Feedstocks

open access: yesAngewandte Chemie, EarlyView.
Heterogeneous iron‐catalyzed environmentally benign and sustainable CH‐oxidative esterification methodology has been developed for the synthesis of esters. This challenging reaction has been achieved by the rational design of specific single atom iron‐based catalyst with Fe‐N4 active centers, which empowered the oxidative esterification of methyl and ...
Zhuang Ma   +8 more
wiley   +1 more source

Identifying the Thermodynamic Driving Force of Metal Extraction by Hydrophobic Eutectic Solvents. [PDF]

open access: yesChemSusChem
Vaz ICM   +11 more
europepmc   +1 more source

Polarity‐Directed Synthesis of an Exfoliable 2D Polyoxometalate‐Based Metal‐Organic Framework for Noble Metal‐Free Alkyne Transfer Semi‐Hydrogenation

open access: yesAngewandte Chemie, EarlyView.
Exfoliation of 2D nanosheets based on polyoxometalate metal‐organic frameworks (POMOFs) gives access to nanostructures with selective catalytic reactivity for the alkyne transfer semi‐hydrogenation which outperform the bulk references and rival some classical noble metal‐based catalysts.
Xusheng Dai   +10 more
wiley   +1 more source

Matching the Coupling of Valence Electrons in the Oxide Interface to Perturb the Magnetic Order Enhancing Oxygen Reduction in Zinc–Air Batteries

open access: yesAngewandte Chemie, EarlyView.
Sub‐5 nm Fe2O3/Sm2O3 heterojunction nanoparticles are anchored on nitrogen‐doped carbon nanofibers, featuring coupled Fe(3d)‐O(2p)‐Sm(4f) orbitals at the interface. The resulting super‐exchange induces antiparallel magnetic ordering at heterointerfaces, suppressing spin‐dependent interaction between surface OH* species and Fe sites to facilitate OH ...
Jing Li   +9 more
wiley   +1 more source

Saturation of superconductivity in cuprates overdoped with high-pressure oxygen: Phase diagram with YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7+δ</sub>, δ → 1. [PDF]

open access: yesProc Natl Acad Sci U S A
Conradson SD   +12 more
europepmc   +1 more source

Strain Engineering via W–O–Ru Interfacial Coupling to Suppress Lattice Oxygen Activation for Stable Acidic Water Electrolysis

open access: yesAngewandte Chemie, EarlyView.
Constructing atomically coupled W–O–Ru interfacial units on RuO2 triggers a dynamic strain evolution during the oxygen evolution reaction. An initial tensile strain secures structural stability, while a self‐adjusting transition to interfacial compression optimizes catalytic activity.
Yi Guan   +7 more
wiley   +1 more source

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