Results 71 to 80 of about 45,221 (235)

Activating a Metallization Switch for Record Hydrogen Evolution in Single‐Atom Modified Polar MOF Piezocatalysts

open access: yesAdvanced Materials, EarlyView.
ABSTRACT Piezocatalytic hydrogen evolution enables the conversion of mechanical energy into chemical fuels, but its efficiency is constrained by a trade‐off between piezoelectric polarization and electronic conductivity. Strong piezoelectric polarization is essential for sufficient driving force, yet highly polar materials typically suffer from poor ...
Chongyan Hao   +13 more
wiley   +1 more source

Intrazeolite phototopotaxy. EXAFS analysis of precursor 8{W(CO)6}-Na56Y and photooxidation products 16(WO3)-Na56Y and 28(WO3)-Na56Y [PDF]

open access: yes, 1991
The intrazeolite photooxidation chemistry of alpha-cage encapsulated hexacarbonyltungsten(0) in Na56Y with O2, denoted n{W(CO)6}-Na56Y/O2/hv, which has previously been shown to provide a novel synthetic pathway to alpha-cage located tungsten(VI) oxide ...
Bein, Thomas   +3 more
core   +1 more source

Pulsed Electrolysis Prevents Sulfur Poisoning for Sustained Sulfide Valorization

open access: yesAdvanced Materials, EarlyView.
Integrating pulsed electrolysis with Sc‐doped NiFe‐LDH enables sustainable sulfide valorization, achieving >500 h stability, 99.8% efficiency. Moreover, this technology produces high‐purity sulfur and sodium formate, boosting profit by 121% to $1,294.7 per tonne of hydrogen.
Zhiyan Hou   +5 more
wiley   +1 more source

Operando X-ray absorption spectra and mass spectrometry data during hydrogenation of ethylene over palladium nanoparticles

open access: yesData in Brief, 2019
We report the series of Pd K-edge X-ray absorption spectra collected during hydrogenation of ethylene with variable ethylene/hydrogen ratio over carbon supported palladium nanoparticles.
Aram L. Bugaev   +7 more
doaj   +1 more source

Inert Catalytic Sites Unlocked by Micropollutants for Rapid Water Decontamination with Near‐Complete Chemical Utilization

open access: yesAdvanced Materials, EarlyView.
Micropollutants can act as molecular triggers that activate a newly designed and chemically inert Fenton‐like PKU‐24 catalyst for on‐demand singlet oxygen generation from peroxymonosulfate (PMS), enabling nearly complete peroxide utilization and selective micropollutant removal from complex real‐world wastewater.
Yu‐Hang Li   +7 more
wiley   +1 more source

Local Lattice Instability and Superconductivity in La$_{1.85}$Sr$_{0.15}$Cu$_{1-x}$M$_x$O$_4$ (M=Mn, Ni, and Co)

open access: yes, 2009
Local lattice structures of La$_{1.85}$Sr$_{0.15}$Cu$_{1-x}$M$_x$O$_4$ (M=Mn, Ni, and Co) single crystals are investigated by polarized extended x-ray absorption fine structure (EXAFS).
Oyanagi, H., Zhang, C. J.
core   +1 more source

Insights into the Structure of Dot@Rod and Dot@Octapod CdSe@CdS Heterostructures [PDF]

open access: yes, 2015
CdSe@CdS dot@rods with diameter around 6 nm and length of either 20, 27, or 30 nm and dot@octapods with pod diameters of ?15 nm and lengths of ?50 nm were investigated by X-ray absorption spectroscopy.
Anna Corrias   +10 more
core   +2 more sources

Boosting Seawater Desalination by Ampere‐Level Nitrate Electroreduction On Defect‐Rich Ultrathin RuCu Alloy Nanostructures

open access: yesAdvanced Materials, EarlyView.
Defect engineering of ultrathin RuCu alloy nanostructures has been successfully achieved to enhance ammonia electrosynthesis under indutrial‐level current density. Simultaneously, the stable ampere‐level operation of nitrate electroreduction on defective RuCu nanostructures can drive seawater desalination at an ultrafast salt removal rate, offering an ...
Juan Wang   +15 more
wiley   +1 more source

Identification of YdhV as the first molybdoenzyme binding a Bis-Mo-MPT cofactor in escherichia coli [PDF]

open access: yes, 2019
The oxidoreductase YdhV in Escherichia coli has been predicted to belong to the family of molybdenum/tungsten cofactor (Moco/Wco)-containing enzymes. In this study, we characterized the YdhV protein in detail, which shares amino acid sequence homology ...
Dau, Holger   +7 more
core   +1 more source

Wafer‐Scale 2D High‐Entropy Transition Metal Dichalcogenide Thin‐Film Catalysts for Efficient and Durable Photoelectrochemical Hydrogen Production

open access: yesAdvanced Materials, EarlyView.
A wafer‐scale 2D high‐entropy (MoWTaNbRu)S2 thin‐film catalyst with a distorted 1T phase integrated onto p‐Si photocathode is designed for highly efficient and durable photoelectrochemical hydrogen evolution reaction. The high‐entropy effect in layered transition metal dichalcogenides optimizes hydrogen adsorption energetics, accelerates photogenerated
Sang Eon Jun   +14 more
wiley   +1 more source

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