Results 71 to 80 of about 23,193 (311)

Improving sensitivity of XANES structural fit to the bridged metal–metal coordination

Journal of Synchrotron Radiation
Hard X-ray absorption spectroscopy is a valuable in situ probe for non-destructive diagnostics of metal sites. The low-energy interval of a spectrum (XANES) contains information about the metal oxidation state, ligand type, symmetry and distances in the ...
S. V. Abrosimov, B. O. Protsenko, A. S. Mannaa, V. G. Vlasenko, S. A. Guda, I. A. Pankin, A. S. Burlov, Y. V. Koshchienko, A. A. Guda, A. V. Soldatov   +9 more
doaj   +1 more source

Laplace‐Pressure‐Stabilized Rutile Solid‐Solution Catalysts for Acidic Water Oxidation: Enabling DSA‐Inspired Compositions

Advanced Materials, EarlyView.
The miscibility of foreign elements in rutile‐type IrO2 and SnO2 is greatly enhanced under high Laplace pressure, where their crystal size is reduced to the nanoscale. This enhancement leads to the successful synthesis of DSA‐composition solid‐solution nanocatalysts with notable durability during the acidic OER in water electrolysis.
Chang Hyun Park, Juneseo Ahn, Dongho Kim, Hyeonsoo Wi, Ki Hyun Park, Jun Seop Kim, Sangmyeong Lee, Sung‐Yoon Chung   +7 more
wiley   +1 more source

Operando X-ray absorption spectra and mass spectrometry data during hydrogenation of ethylene over palladium nanoparticles

Data in Brief, 2019
We report the series of Pd K-edge X-ray absorption spectra collected during hydrogenation of ethylene with variable ethylene/hydrogen ratio over carbon supported palladium nanoparticles.
Aram L. Bugaev, Alexander A. Guda, Ilia A. Pankin, Elena Groppo, Riccardo Pellegrini, Alessandro Longo, Alexander V. Soldatov, Carlo Lamberti   +7 more
doaj   +1 more source

Exafs Studies of Multilayer Interfaces

, 1988
Important for the understanding of multilayer materials is a determination of their interface structure. The extended x-ray absorption fine structure (EXAFS) technique can be useful, particularly for interfaces with a high degree of structural disorder ...
G. M. Lamble, S. M. Heald
core   +1 more source

Co1/Ru Single‐Atom Alloy Catalyst for Sustainable Polypropylene Hydrogenolysis to Long‐Chain Liquid Products

Advanced Materials, EarlyView.
A titania‐supported Co1/Ru single‐atom alloy catalyst enables efficient polypropylene hydrogenolysis. Ru─Co─Ru motifs maintain Ru activity while suppressing excessive chain scission to gaseous products. Both virgin and waste plastics achieve high, environmentally and economically optimal C11+ liquid yields, supporting sustainable chemical recycling ...
Yuzhen Ge, Yimeng Jin, Alexandra Krestnikova, Sibei Zou, Antonio J. Martín, Gonzalo Guillén‐Gosálbez, Javier Pérez‐Ramírez   +6 more
wiley   +1 more source

Transient Laser‐Shocked Synthesis of Amorphous Layer‐Supported Metal Nanocrystals for Efficient Nitrate Reduction

Advanced Materials, EarlyView.
A general, versatile laser‐shock synthesis process is reported to produce various bimetallic CuNi, CuFe, CuCo, and medium‐entropy CuFeCoNi heterostructures, in which crystalline metal nanoparticles are anchored to amorphous hydroxide supports. During nitrate reduction reaction, the heterostructures undergo dynamic amorphous/crystalline reconstruction ...
Weihua Guo, Jixun Zhang, Siwei Zhang, Yangbo Ma, Yun Song, Jianjun Su, Zihao Li, Yinger Xin, Qiang Zhang, Mingming He, Ruixuan Wang, Rui Xue, Shibo Xi, Ying Wang, Shenlong Zhao, Tao Yang, Zhengxiao Guo, Ben Zhong Tang, Ruquan Ye   +18 more
wiley   +1 more source

Engineering CO2 Reduction Pathways via Alloy‐Support Interactions in Li‐CO2 Batteries

Advanced Materials, EarlyView.
Alloy‐support interactions in RuCu/NC induce interfacial charge redistribution and shift d‐band centers, steering CO2 reduction from Li2CO3 to metastable Li2C2O4. This pathway engineering lowers the rate‐determining barrier and suppresses carbonate formation, enabling high discharge voltage (3.23 V) in Li‐CO2 batteries with reduced overpotential (0.50 ...
Liang Sun, Xindan Zhang, Guang Feng, Guoqiang Zhao, Bernt Johannessen, Guanjie Li, Shilin Zhang, Hongge Pan, Zaiping Guo   +8 more
wiley   +1 more source

X-ray absorption spectroscopy of Mn doped ZnO thin films prepared by rf sputtering technique

AIP Advances, 2015
A set of r.f. sputter deposited ZnO thin films prepared with different Mn doping concentrations have been characterised by Extended X-ray Absorption Fine Structure (EXAFS) and X-ray Absorption Near Edge Spectroscopy (XANES) measurements at Zn, Mn and O K
Ashok Kumar Yadav, Sk Maidul Haque, Dinesh Shukla, Ram Janay Choudhary, S. N. Jha, D. Bhattacharyya   +5 more
doaj   +1 more source

Speciation of Ruthenium(III) Chloro Complexes in Hydrochloric Acid Solutions and Their Extraction Characteristics with an Amide-Containing Amine Compound

Metals, 2018
The refining of platinum group metals is based mainly on solvent extraction methods, whereas Ru is selectively recovered by distillation as RuO4. Replacement of distillation by extraction is expected to simplify the purification process.
Tomoya Suzuki, Takeshi Ogata, Mikiya Tanaka, Tohru Kobayashi, Hideaki Shiwaku, Tsuyoshi Yaita, Hirokazu Narita   +6 more
doaj   +1 more source

X-ray powder diffraction and EXAFS studies on SnAPO-5 and Cu:SnAPO-5

, 2001
SnAPO-5 was synthesised and calcined at 800 degreesC. Copper was introduced into the calcined material by the incipient wetness method. The as-synthesised, calcined and copper-incorporated SnAPO-5 have been studied using X-ray powder diffraction and ...
Ståhl K, Flavell WR, Nilsen, M. H., Nilsen MH, Ståhl, Kenny, Ståhl, K., Nicholson, D. G., Flavell, W. R.; id_orcid, Flavell, W. R., Nicholson DG   +9 more
core   +1 more source