Results 71 to 80 of about 484 (218)

THE EXAFS OF QUASICRYSTALS

open access: yesLe Journal de Physique Colloques, 1986
EXAFS data for a number of Al-based quasicrystalline alloys are surveyed. A comparative EXAFS study of icosahedral Al86 Mn14, Al85 Mn7 Cr8 and Al86 Cr14 phases is presented in detail. To interpret the EXAFS results, an icosahedral model is proposed in the framework of the α (Al Mn Si) structure and in close relation to recent theories of Mackay ...
openaire   +1 more source

Efficient Direct Recycling of Spent Batteries: Integrated Lithiation and Delamination

open access: yesAdvanced Science, EarlyView.
An integrated process for the delamination and relithiation of spent cathodes, LixNi0.6Co0.2Mn0.2O2 and LixFePO4, under open‐air conditions is proposed. The transition‐metal (Ni) oxidation state in the cathode is reduced by the oxidation of diethylene glycol, facilitating relithiation. Glycol aldehyde formation induces 100% electrode delamination.
Jeonghwan Song   +11 more
wiley   +1 more source

Sorption Speciation of Lanthanides/Actinides on Minerals by TRLFS, EXAFS and DFT Studies: A Review

open access: yesMolecules, 2010
Lanthanides/actinides sorption speciation on minerals and oxides by means of time resolved laser fluorescence spectroscopy (TRLFS), extended X-ray absorption fine structure spectroscopy (EXAFS) and density functional theory (DFT) is reviewed in the field
Xiaoli Tan, Ming Fang, Xiangke Wang
doaj   +1 more source

Near‐Unity Selectivity Inversion Between CO2 Electroreduction and H2 Evolution via Atomic Coordination Editing

open access: yesAdvanced Science, EarlyView.
Atomic coordination editing functions as an on/off switch that toggles single‐atom catalysts between CO2 electroreduction and hydrogen evolution. ABSTRACT Precise atomic coordination editing of single‐atom catalysts (SACs) provides an effective strategy to tune their electronic structures and catalytic selectivity. Yet, achieving near‐unity selectivity
Yukun Zhao   +11 more
wiley   +1 more source

Hyperspectral full-field quick-EXAFS imaging at the ROCK beamline for monitoring micrometre-sized heterogeneity of functional materials under process conditions

open access: yesJournal of Synchrotron Radiation
Full-field transmission X-ray microscopy has been recently implemented at the hard X-ray ROCK–SOLEIL quick-EXAFS beamline, adding micrometre spatial resolution to the second time resolution characterizing the beamline.
Valérie Briois   +11 more
doaj   +1 more source

Robust Amorphous MOF‐Based Aerogels Digital Biosensor for Sensitive Detection of Organophosphate Pesticides

open access: yesAdvanced Science, EarlyView.
We report a robust aerogel digital biosensor by integrating an enzyme‐mediated amorphous MOF within an aerogel matrix for on‐site pesticide detection. The enzyme‐mediated assembly strategy enables in situ tailoring of MOF into a porous amorphous structure, achieving both high stability and activity.
Changshun Su   +7 more
wiley   +1 more source

Biological EXAFS at room temperature

open access: yesJournal of Synchrotron Radiation, 1999
Biological EXAFS experiments are usually carried out on frozen samples in order to minimize radiation damage. This causes difficulties when studies at different pH are made, since the pH cannot be measured directly for the frozen sample. We have carried out EXAFS studies of Human Carbonic Anhydrase, a zinc metalloenzyme, at room temperature using a ...
J C, Amiss, S J, Gurman
openaire   +2 more sources

Atomic‐Level CuOx‐CoOx‐Pd Interfacial Engineering Enables Hierarchical Synergy for High‐Efficiency ORR Pathways and Boosted Power Output in Alkaline Fuel Cells

open access: yesAdvanced Science, EarlyView.
Atomically dispersed CuOx (CPCu‐1) forms isolated Cu–Ov sites that enable defect‐mediated O2 activation and fast electron/proton transfer via interfacial synergy. In contrast, thick CuOx clusters (CPCu‐10) promote a surface‐adsorption‐controlled pathway with intermediate accumulation, highlighting a mechanism switch from interfacial activation to ...
Yang‐Yang Hsu   +8 more
wiley   +1 more source

Heterostructured Materials for Room‐Temperature Na‐S Batteries: Directional Design Strategies and Multifaceted Applications

open access: yesAdvanced Science, EarlyView.
In this work, heterostructured materials for room‐temperature Na‐S batteries are comprehensively reviewed. The electrochemical mechanisms of Na‐S batteries based on various redox pathways are clarified. The intrinsic functionalities and design principles of heterostructured materials are summarized.
Yeqing Yang   +4 more
wiley   +1 more source

Multiferroic‐Centric Materials and Systems Engineering for Battery Applications: An Insight Into Mechanisms, Strategies, and Characterizations

open access: yesAdvanced Science, EarlyView.
Multiferroic order parameters – polarization, magnetization, and ferroelastic strain – are positioned as dynamic design variables for batteries. Their mechanistic roles, practical tuning through fabrication and external fields, and ferroic‐resolved characterization routes are unified into a closed‐loop framework, revealing how coupled ferroic responses
Jiaqi Su   +13 more
wiley   +1 more source

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