Results 141 to 150 of about 103,476 (250)

Excitonic Polarons and Self-Trapped Excitons from First-Principles Exciton-Phonon Couplings

Physical Review Letters
Excitons consist of electrons and holes held together by their attractive Coulomb interaction. Although excitons are neutral excitations, spatial fluctuations in their charge density couple with the ions of the crystal lattice. This coupling can lower the exciton energy and lead to the formation of a localized excitonic polaron, or even a self-trapped ...
Zhenbang Dai, Chao Lian, Jon Lafuente-Bartolome, Feliciano Giustino   +3 more
openaire   +3 more sources

Highly‐Emissive Organic Photovoltaics Approaching Theoretical Limit Voltage and Enabling Multifunctional Energy‐Harvesting Displays

Advanced Materials, EarlyView.
A highly‐emissive organic photovoltaic employs donor–acceptor pairs with alternately localized frontier molecular orbitals, preserving high triplet energies and small reorganization energies to suppress non‐radiative recombination. As a result, it exhibits a high open‐circuit voltage approaching the Shockley–Queisser limit and a high ...
Qing‐Jun Shui, Naoya Aizawa, Jinyao Xu, Atsuko Nihonyanagi, Daigo Miyajima, Ken‐ichi Nakayama, Yutaka Majima, Seiichiro Izawa   +7 more
wiley   +1 more source

Pressure-controlled free exciton and self-trapped exciton emission in quasi-one-dimensional hybrid lead bromides

Nature Communications
Hybrid metal halides represent a novel type of semiconductor light emitters with intriguing excitonic emission properties, including free exciton emission and self-trapped exciton emission.
Bin Xu, Yawen Li, Peibin Hong, Peijie Zhang, Jiang Han, Zewen Xiao, Zewei Quan   +6 more
doaj   +1 more source

Large‐Scale Determination of Frontier Orbital Energies of Disordered Small‐Molecule Organic Semiconductors Using Exciplex Emission Spectra

Advanced Materials, EarlyView.
ABSTRACT Accurately knowing the frontier orbital energies of the structurally disordered small‐molecule organic semiconductors that are used in optoelectronic devices such as organic light‐emitting diodes is required to rationally improve their performance. Here, we show that these energies can be deduced with a large accuracy from the peak energies of
Christian B. McDonald, Hiroki Tomita, Giacomo Cotelli, Louka L. Brüll, Nanno G. de Rooij, Lucas R.L. Norg, Milo Clément, Reinder Coehoorn   +7 more
wiley   +1 more source

Wafer‐Scale 2D High‐Entropy Transition Metal Dichalcogenide Thin‐Film Catalysts for Efficient and Durable Photoelectrochemical Hydrogen Production

Advanced Materials, EarlyView.
A wafer‐scale 2D high‐entropy (MoWTaNbRu)S2 thin‐film catalyst with a distorted 1T phase integrated onto p‐Si photocathode is designed for highly efficient and durable photoelectrochemical hydrogen evolution reaction. The high‐entropy effect in layered transition metal dichalcogenides optimizes hydrogen adsorption energetics, accelerates photogenerated
Sang Eon Jun, Jin Ho Seo, Jaehyun Kim, Hyungsoo Lee, Seongbeen Kim, Woo Seok Cheon, Sabina Kim, In Hye Kwak, Byeong‐Gwan Cho, Ki Chang Kwon, Chul‐Ho Lee, Jungwon Park, Jooho Moon, Jennifer A. Dionne, Ho Won Jang   +14 more
wiley   +1 more source

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

Advanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen, Zhanxi Fan, Jingjie Ge, Qiyuan He, Zhuangchai Lai, Jiawei Liu, Chaoliang Tan, Hua Zhang   +7 more
wiley   +1 more source

Tailoring the Morphology of MoS2 using RF Magnetron Sputtering for Enhanced Photoelectrochemical Water Splitting

Advanced Materials Interfaces, EarlyView.
Tailoring the morphology of MoS2 using RF Magnetron Sputtering for Enhanced Photoelectrochemical Water Splitting. ABSTRACT 2D molybdenum disulfide (MoS2) is a promising material for optoelectronic and photoelectrochemical (PEC) applications due to its unique properties.
Somnath Ladhane, Shruti Shah, Jyoti Thombare, Mansi Ingole, Swati Rahane, Priti Vairale, Vidya Doiphode, Yogesh Hase, Shashikant P. Patole, Sandesh Jadkar   +9 more
wiley   +1 more source

Surface‐Ligand‐Dependent Excited‐State Dynamics in Aqueous CuInSe2/ZnS Quantum Dot–Chlorophyll Assemblies

Advanced Materials Interfaces, EarlyView.
CuInSe2/ZnS quantum dots are synthesized in water and coupled with chlorophyll to probe ligand‐controlled excited‐state interactions. Broad visible–NIR emission and high PLQY are observed. Time‐resolved measurements reveal shortened chlorophyll lifetimes, indicating dynamic quenching via Förster energy and/or charge transfer, highlighting surface ...
Özge İbiş, Hadi Jahangiri, Elif Çeltek, Caner Ünlü   +3 more
wiley   +1 more source

Advances in Halide Perovskites for Photon Radiation Detectors

Advanced Materials Technologies, EarlyView.
This work highlights recent progress in perovskite‐based photon radiation detectors, covering organic–inorganic hybrid, inorganic, lead‐free double, and vacancy‐ordered halide perovskites. Their detection performance is compared, material‐specific advantages and challenges are examined, and provides insight into current limitations and future ...
Liangling Wang, Jieqi Wang, Xiaojun Cui, Carsten Ronning   +3 more
wiley   +1 more source

Highly Anisotropic Quasi‐Direct Organic Metal Halide Hybrids: A Platform for Polarization‐Sensitive Optoelectronics

Advanced Materials Technologies, EarlyView.
One‐dimensional C4N2H14PbBr4 is shown to have a quasi‐direct electronic band structure and strongly anisotropic transport with polarized broadband emission. A GW/Bethe–Salpeter excited‐state force formalism, supported by polarized Raman and temperature‐dependent photoluminescence, identifies low–frequency Pb–Br phonons that drive ultrafast exciton self‐
Rijan Karkee, Rafael R. Del Grande, Yeonjoo Lee, Jinkyoung Yoo, Azza Ben‐Akacha, Biwu Ma, Michael T. Pettes, David A. Strubbe   +7 more
wiley   +1 more source