Results 141 to 150 of about 2,584,295 (232)

Dimensional Reduction of Transition Metal Dichalcogenides by Oxide Insertion: Quasi‐1D Oxychalcogenide Semiconductors

Angewandte Chemie, EarlyView.
Molecular Scissors: Oxide insertion slices the layers of MQ2 transition metal dichalcogenides (TMDs) into one‐dimensional [M3Q6] nanoribbons, giving a new family of A2Hf3Q6O (A = K, Rb, Cs; Q = S, Se) oxychalcogenides. The heteroanion‐driven dimensional reduction yields direct‐gap semiconductors with optical absorption that is tunable across the ...
Ayat Tassanov, Azamat Yessengazin, Huiju Lee, Pedro R. Trinidad‐Pérez, Daniel G. Chica, Yi Xia, James M. Hodges   +6 more
wiley   +2 more sources

Reverse Haptic Alerting: Human‐Centered Intelligent Systems That Turn Chemical and Biomedical Signals Into Felt Cues

Advanced Intelligent Systems, EarlyView.
Wearable sensors usually warn through sight or sound, channels that become unreliable under protective equipment or in noise. Reverse haptic alerting inverts this flow: Stimuli‐responsive materials convert chemical and biological signals into cues felt through the skin, while a machine‐learned digital twin of tactile perception personalizes the body ...
Hwanhee Yoo, Shin Hum Cho, Ku Kang, Yoon Jeong Jang, Chan‐Mo Yang, Doo‐Hee Lee   +5 more
wiley   +1 more source

Mechanochemical Defluorination of Polytetrafluoroethylene (PTFE) With Base Metals

Angewandte Chemie, EarlyView.
Polytetrafluoroethylene (PTFE) mechanochemically reacts with safe‐to‐handle, abundant, and inexpensive base metals Zn and Al, as well as with metals like Cd and Pb, to produce sp2‐carbon and industrially important metal fluorides. The reactivity presents PTFE as a mechanochemical fluorination agent, with opportunities for closed‐loop reductive ...
Anže Zupanc, A. R. Bonnie J. Lutton Gething, Alex J. Green, Shrestha Banerjee, Moosa Wasim, Luis Simbari, Benjamin B. Duff, Peter R. Slater, Dominik J. Kubicki, Erli Lu, Tomislav Friščić   +10 more
wiley   +2 more sources

Numerical investigation and ANN-assisted prediction of temperature amplitude and radiative heat transfer performance of MHD gold-water nanofluid over thin-walled heat exchanger plate. [PDF]

Discov Nano
Salih AAM, Ullah Z, Merga FE, Benaissa M, Ghernaout D, Marzouki R, Ben Khedher N.   +6 more
europepmc   +1 more source

Disorder Beats Order: Carbon Microstructure Steers Radical Versus Cationic Pathways in Kolbe Electrolysis

Angewandte Chemie, EarlyView.
Less graphitic, more Kolbe: carbon microstructure steers selectivity in Kolbe electrolysis. Disordered, sp3‐rich carbon electrodes with high charge‐transfer resistance favor surface radical pathways, giving about an order of magnitude more Kolbe dimer than graphitized sp2‐rich counterparts.
Md Mosaddek Hossen, Thy Ho, Bin Wang, Jean‐Philippe Tessonnier   +3 more
wiley   +2 more sources

Elucidating the Molecular Interactions of Flavonoid-Metal Complexes via Isothermal Titration Calorimetry. [PDF]

Biomolecules
Guerrero M, Kim A, Braden C, Bao Y.
europepmc   +1 more source

Double Reduction of Ph3B to a Dianionic Borane With a Powerful SrI Intermediate

Angewandte Chemie, EarlyView.
Although dianionic boranes follow the octet rule and are isoelectronic to carbanions or amines, the high electron density combined with the electropositive nature of the B center make them highly unstable species. In this study, we present synthesis and full characterization of a complex in which Ph3B2− is sandwiched between two Sr2+ ions and describe ...
Michael Morasch, Marcel A. Schmidt, Tanuja Tewari, Jens Langer, Sjoerd Harder   +4 more
wiley   +2 more sources

Operando X‐Ray Micro‐Imaging Reveals Spatiotemporal Evolution of the Oxidation State of Nickel During Dry Methane Reforming

Angewandte Chemie, EarlyView.
Operando X‐ray micro‐imaging enables quantitative determination of spatially resolved nickel redox rates during the process of dry reforming of methane and its subsequent regeneration. The support composition governs the local nickel redox dynamics, thereby exhibiting different local nickel reduction and oxidation rates. The spatiotemporal Ni oxidation
Sofie Ferwerda, Valerie Briois, Anthony Beauvois, Sebastian Weber, Nils Bottke, Matteo Monai, Bert M. Weckhuysen   +6 more
wiley   +2 more sources

Synthesis of trifluoroacetic acid encapsulated aluminium nanoparticles and reactivity characterisation <i>via</i> Al/CuO nanothermites. [PDF]

RSC Adv
Cheng YS, Huang CW, Wu MH, Hsu WL.
europepmc   +1 more source

Polypyridyl Coordination Motifs as Precursors for Ordered Carbonaceous Frameworks Toward High‐Density Ru Single‐Atom Catalysts

Angewandte Chemie, EarlyView.
Here, we introduce a molecular design principle that fundamentally expands the bottom‐up synthesis of single‐atom catalysts (SACs). Coordinatively flexible polypyridyl units enable bottom‐up formation of ordered carbonaceous frameworks containing atomically dispersed Ru (∼11 wt%) by simple carbonization.
Koki Chida, Tan‐Hao Shi, Takeharu Yoshii, Yuichiro Hayasaka, Yu Gao, Hao Zhang, Nikolay Kosinov, Shigehisa Akine, Kazuhide Kamiya, Kaining Li, Yoshifumi Kondo, Yasutaka Kuwahara, Tomoki Ogoshi, Hirotomo Nishihara   +13 more
wiley   +2 more sources