Results 161 to 170 of about 592,772 (239)

Revealing the Nature of Non‐Covalent Interactions in Ionic Liquids by Combined Pulse EPR and 19F NMR Spectroscopy

open access: yesAngewandte Chemie, EarlyView.
Ionic liquids have been proposed as alternatives to molecular solvents. Here, spin probes and spin‐labelled ILs are studied by pulse electron paramagnetic resonance, paramagnetic relaxation enhancement NMR, molecular dynamics, and density functional theory, revealing the IL interaction sphere. The results challenge previous interpretations of nitroxide‐
Ciarán J. Rogers   +6 more
wiley   +2 more sources

HCN2‐Associated Neurodevelopmental Disorders: Data from Patients and Xenopus Cell Models

open access: yesAnnals of Neurology, EarlyView.
Objective We aimed to characterize the phenotypic spectrum and functional consequences associated with variants in HCN2, encoding for the hyperpolarization‐activated cyclic nucleotide (HCN) gated channel 2. Methods GeneMatcher facilitated the recruitment of 21 individuals with HCN2 variants from 15 unrelated families, carrying HCN2 variants.
Clara Houdayer   +52 more
wiley   +1 more source

Cooperativity of Electron Transfer Coupled Spin Transitions in a Tetranuclear Fe/Co Prussian Blue Analogue Revealed by Ultrafast Spectroscopy

open access: yesAngewandte Chemie, EarlyView.
Ultrafast pump‐probe spectroscopies show that irradiation of a square Fe/Co Prussian blue analogue induces electron transfer within one Fe–Co subunit followed by fast spin crossover, and coupled equilibria between all states trigger a second electron transfer coupled to spin crossover in the other Fe–Co subunit on a ns timescale.
Jan‐Hendrik Borter   +8 more
wiley   +2 more sources

Stochastic Hydrodynamic Velocity Field and the Representation of Langevin Equations

open access: yesAnnalen der Physik, EarlyView.
A lumped method is proposed to account for both mean‐field hydrodynamics and stochastic fluctuations within the kinematic equations of motion, providing a regularized formulation of the overdamped approximation. The concept of stochastic realizability in broad sense is introduced based on the spectral properties of the Fredholm operator associated with
Massimiliano Giona   +2 more
wiley   +1 more source

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