1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic +4 more
wiley +2 more sources
Insights on Acute and Chronic Lacquer Cracks as Imaged with Visible Light OCT. [PDF]
Hu G +4 more
europepmc +1 more source
Elucidating the Structure-Nonlinear Optical Property Relationship of Ethynyl Extended Benzanthrone Chromophores. [PDF]
Gouda DJ +6 more
europepmc +1 more source
CLEM-Reg: an automated point cloud-based registration algorithm for volume correlative light and electron microscopy. [PDF]
Krentzel D +8 more
europepmc +1 more source
A linear polymer, poly(2,3‐dihydroxynaphthalene), when insolubilized, leads to self‐assembly into a hydroquinone–quinone donor+acceptor semiconducting architecture through H‐bonding and π‐stacking interactions. The polymer behaves as a heterogeneous photocatalyst in water for H2O2 production via water oxidation and O2 reduction under visible light.
Koki Yoshida +4 more
wiley +1 more source
Crystal structure, Hirshfeld surface analysis of 2-(eth-oxy-carbon-yl)quinolinium tetra-chlorido(quinoline-2-carboxyl-ato-κ<sup>2</sup> <i>N</i>,<i>O</i>)stannate(IV) monohydrate. [PDF]
Benlatreche T +3 more
europepmc +1 more source
Contextual Modulation of Semantic Coherence in vmPFC Patients' Mental Constructions. [PDF]
Stendardi D +5 more
europepmc +1 more source
A Chiral Saddle‐Shaped Nanographene With Two Heptagon‐Embedded [4]Helicenes
We present a novel synthetic strategy toward a chiral saddle‐shaped nanographene (cSNG) via a two‐step oxidation of a prochiral anthracene precursor. The Scholl‐type oxidation first yields a key intermediate with sp3‐defect heptagons, and subsequent oxidative dehydrogenation affords fully conjugated cSNG.
Felix Trautner +11 more
wiley +1 more source
Comparative Anatomy of the Hyoid Apparatus in Various Dog Breeds: Insights From Clinical Imaging. [PDF]
Altundağ Y +6 more
europepmc +1 more source
Controlling the Guanidinium Cation Rotation by Cation–π Interactions
A lanthanide π‐container has been employed to trap a guanidinium cation inside the aromatic cavity by cation–π interactions. X‐ray crystallography and solid‐state nuclear magnetic resonance (NMR) spectroscopy at fast magic‐angle spinning (MAS) frequencies have been utilized to probe the underlying host–guest interactions.
Hannah Busch +12 more
wiley +1 more source

