Results 141 to 150 of about 9,510 (195)

Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation

Angewandte Chemie, EarlyView.
Unlocking gallyl nucleophiles: Counterion control enables formation of an unsupported gallyl─gold complex. Gold coordination induces a polarity switch at gallium, enabling cooperative activation of NH3 and related N─H/O─H substrates under mild conditions.
Hellen Videa, Keelan M. Byrne, Tobias Krämer, Antonio J. Martínez‐Martínez   +3 more
wiley   +2 more sources

Three-dimensional bulk reduced graphene oxide coatings with strong metal adhesion via cold plasma and pulsed current. [PDF]

Sci Rep
Zimniak Z, Tylus W, Borak B, Pachnicz M, Rutkowska-Gorczyca M, Wróblewski R, Kobiela K, Dusza D.   +7 more
europepmc   +1 more source

1,4‐Digermacyclopenta‐1,3‐diene: Continuous Cyclic σ*–π Delocalization Enables Aromatic Stabilization in a Heavy‐Element 4π System

Angewandte Chemie, EarlyView.
A five‐membered digermacycle exhibits an unusual 4π electron delocalization enabled by σ*(Ge–C)–π coupling within a nearly planar framework. Combined experimental and theoretical analyses reveal a continuous cyclic delocalization pathway, highlighting σ*–π interactions as a design principle for aromatic stabilization beyond classical π‐conjugated ...
Daichi Uchida, Hiroko Yamada, Yoshiyuki Mizuhata   +2 more
wiley   +2 more sources

Tandem Reactivity of Metal−Carbon and Carbon−Silicon Bonds in Mononuclear α‐Silyl Organolithium or Organosodium Complexes Towards CO, CO2 and Heteroallenes

Angewandte Chemie, EarlyView.
Anionic α‐silyl alkyl is one of the most used organometallic building blocks and funtional groups. Traditionally, the C─Si bond in these complexes is considered as inert. In this work, we report a series of reactions between mononuclear organo‐lithium and ‐sodium complexes with CO, CO2, or heteroallenes.
Xiao Yang, Jack M. Hemingway, Wataru Kanna, Nathan Davison, Hiroki Hayashi, Louise Male, Paul G. Waddell, James A. Dawson, Erli Lu   +8 more
wiley   +2 more sources

Combination of extracellular vesicles and organoids as a prospective model for cancer research (Review). [PDF]

Oncol Lett
Cao J, Xu Y, Gao Y, Li X, Wang L.
europepmc   +1 more source

Circularly Polarized Luminescent and Melt‐Processable Copper(I)‐Organic Glasses Based on 2,2′‐Bis(diphenylphosphino)‐1,1′‐binaphthyl

Angewandte Chemie, EarlyView.
Homochiral Cu(I) cyanide complexes based on 2,2’‐bis(diphenylphosphino)‐1,1’‐binaphthyl (BINAP) form melt‐quenched and desolvation‐derived metal–organic glasses that exhibit circularly polarized thermally activated delayed fluorescence (TADF) at room temperature, enabling processable chiroptical materials.
Zeyu Fan, Indranil Sen, Roman Pallach, Guo‐Qiang Li, Andreas Steffen, Sebastian Henke   +5 more
wiley   +2 more sources

Inertial motion of a circular cylinder approaching obliquely an ice cover. [PDF]

Sci Rep
Xiong H, Ni B, Semenov Y, Korobkin A.
europepmc   +1 more source

Inulin-Based Oral Chemotherapy Modulates Gut Microbiota and Immune Microenvironment through Inhibition of Neutrophil Extracellular Trap Formation for Improving Cancer Therapy. [PDF]

Adv Sci (Weinh)
Li Z, Jiang J, Zhou Y, Mao X, Wen H, Chen Z, Wang Y, Huang C, Hu Y.   +8 more
europepmc   +1 more source

Molecular Dynamics Study of the Coalescence of Water Droplets with Anionic Asphaltene Molecules under a DC Electric Field. [PDF]

Langmuir
Lange Bregado J, Secchi AR, Nele M.
europepmc   +1 more source

Tips versus Holes: ×10 Higher Scattering in FIB-made Plasmonic Nanoscale Arrays for Spectral Imaging. [PDF]

ACS Omega
Mandelbaum Y, Tkachev M, Sanjeev A, Zalevsky Z, Zitoun D, Karsenty A.   +5 more
europepmc   +1 more source