Mechanistic Diversity in Photoexcited Radical Redox Chemistry: A Critical Evaluation
Many high‐profile examples of photoredox catalysis are proposed to proceed via excitation of an open‐shell intermediate form of the catalyst. However, there is much debate over whether such mechanisms are realistic and, if so, exactly how they can occur.
Samuel J. Horsewill +3 more
wiley +1 more source
Modeling constrained tumor evolution through hybrid Ornstein-Uhlenbeck and branching dynamics. [PDF]
Kim SH.
europepmc +1 more source
Silent regulators of trauma: the microRNA blueprint underlying post-traumatic stress disorder biology. [PDF]
Dwivedi Y, Prall K, Shelton RC.
europepmc +1 more source
Lower speciation, not higher extinction, drove African megaherbivore diversity collapse. [PDF]
Cantalapiedra JL +10 more
europepmc +1 more source
Insights from three decades of IUCN Red List assessments catalyzing shark, ray, and chimaera conservation. [PDF]
Finucci B +10 more
europepmc +1 more source
Models used for Red List assessments underestimate climate-related extinction risk of range-shifting species. [PDF]
Keuth R, Fritz SA, Zurell D.
europepmc +1 more source
Uncaging Iridium(III) Complexes for Combined Photodynamic and Photoactivated Chemotherapy
Light‐activatable iridium(III) anticancer prodrugs demonstrate how chalcogen coordination controls photoinduced therapeutic activity. Upon visible‐light irradiation, sulfur‐ and selenium‐based caging ligands undergo distinct oxygen‐dependent photoreactions that trigger ligand release and singlet oxygen generation, enabling combined photoactivated ...
Victoria V. L. Müller +5 more
wiley +1 more source
Sexually dimorphic effects of single prolonged stress on conditioned suppression behavior in Long Evans rats with no detection of altered mRNA expression of VGLUT1, GAD1, and Arc in the ventral hippocampus. [PDF]
Pitcairn SR +3 more
europepmc +1 more source
Abstract The Pleistocene is a key period for understanding the evolutionary history and palaeobiogeography of the European rabbit (Oryctolagus cuniculus). The species was first documented in southeastern Iberia at the beginning of the Middle Pleistocene and appears to have rapidly spread throughout Southwestern Europe, where it was found in numerous ...
Maxime Pelletier
wiley +1 more source
When Communication Enables Catastrophe: Nuclear Risk and the Short Lifetimes of Technological Civilizations: A Bayesian Scenario Analysis of Civilizational Survival and the Fermi Paradox. [PDF]
Alfano V.
europepmc +1 more source

