Distribution of micro-amounts of europium in the two-phase water-HCl-nitrobenzene-N,N'-dimethyl-N,N'-diphenyl-2,6-dipicolinamide-hydrogen dicarbollylcobaltate extraction system [PDF]
Extraction of micro-amounts of europium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of N,N'-dimethyl- -N,N'-diphenyl-2,6-dipicolinamide (MePhDPA, L) was investigated.
Makrlík Emanuel +4 more
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Activation of the Aromatic Core of 3,3'-(Pyridine-2,6-diylbis(1H-1,2,3-triazole-4,1-diyl))bis(propan-1-ol)-Effects on Extraction Performance, Stability Constants, and Basicity. [PDF]
The "CHON" compatible water-soluble ligand 3,3'-(pyridine-2,6-diylbis(1H-1,2,3-triazole-4,1-diyl))bis(propan-1-ol) (PTD) has shown promise for selectively stripping actinide ions from an organic phase containing both actinide and lanthanide ions, by preferential complexation of the former.
Weßling P +11 more
europepmc +6 more sources
18-Crown-6 and Dibenzo-18-crown-6 Assisted Extraction of Cesium from Water into Room Temperature Ionic Liquids and Its Correlation with Stability Constants for Cesium Complexes [PDF]
The pH-profiles of the extraction of Cs+ into four conventional (1-butyl-3-methylimidazolium hexafluorophosphate and bis[trifluoromethyl)sulphonyl]imides of 1-butyl-3-methylimidazolium, 1-hexyl-3-methylimidazolium, and 1-(2-ethylhexyl)-3 ...
Igor Vladimirovich Pletnev +6 more
doaj +3 more sources
Solvent extraction of Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, UO22+, Mn2+, Co2+ and Ni2+ into nitrobenzene using strontium dicarbollylcobaltate and tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate [PDF]
The exchange extraction constants corresponding to the general equilibrium M2+(aq) + SrL2+(nb) ← →ML2+(nb) + Sr2+(aq) occurring in the two- -phase water-nitrobenzene system (M2+ = Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, UO22+ , Mn2+, Co2+ or Ni2+; L = tetra ...
Makrlík E. +3 more
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Studies on the separation of some transition metals using trialkylimidazole as selective extractant [PDF]
The possibility of Cu(II) ion separation from an equimolar Cu-Cd-Zn tertiary mixture by solvent extraction was investigated. The process was based on the use of 1,2,4-trimethylimidazole (TMI) and 1- decyl-2,4-dimethylimidazole (DDMI) as extractant ...
Radzyminska-Lenarcik Elzbieta +1 more
doaj +2 more sources
Calcium ionophore I as very effective extraction agent for trivalent europium and americium [PDF]
The solvent extraction of microamounts of Eu3+ and Am3+ from water into nitrobenzene by means of a mixture of hydrogen dicarbollylcobaltate (H+B-) and calcium ionophore I (marked as the ligand L) was investigated. The equilibrium data have been explained
Makrlík Emanuel, Vaňura Petr
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Solvent extraction of trivalent europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate and tetraisopropyl[oxybis(2,1-ethanediyliminocarbonyl)]-bisphosphoramidate [PDF]
Solvent extraction of micro-amounts of Eu3+ and Am3+ from water into nitrobenzene by means of a mixture of hydrogen dicarbollylcobaltate (H+B-) and tetraisopropyl[oxybis(2,1-ethanediyliminocarbonyl)]-bisphosphoramidate (L) was studied.
Makrlík Emanuel +3 more
doaj +1 more source
The Stability Constants of Nickel(II) Complexes with Chloride, Thiocyanate, Sulfate, Thiosulfate, and Oxalate Ions, as Determined by a Solvent Extraction Method [PDF]
Abstract The stability constants of nickel(II) complexes in 1 mol dm−3 sodium perchlorate media were determined at 25 °C by means of a solvent extraction method. The values thus obtained for logβ1 and logβ2 are: 0.0 and no second complex (Cl−), 1.1 and 1.6 (SCN−), 1.0 and 1.4 (SO42−), 0.9 and 1.3 (S2O32−), and 3.7 and 6.6 (C2O42 ...
Ryokichi Murai +2 more
openaire +1 more source
The correlation of the values of plant-available lead and cadmium in soil determined using different types of extragents [PDF]
The plant-available amount of Pb and Cd in soil was determined by extraction using the solutions: 1) 0.5MNa2EDTA, pH5.2; 2)1M KCl, pH7.0; 3)0.1M KCl, 0.05 MNa2EDTA, pH 6.2; 4) 2 % CH3COOH, pH 2.5 and 5) 1M CH3COONH4, pH 4.8.
Savin Ankica +2 more
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Cd(II) extraction in PEG (1550)–(NH4)2SO4 aqueous two-phase systems using halide extractants [PDF]
The extraction of Cd(II) was studied in an aqueous PEG–(NH4)2SO4 two-phase system, formed from a water-soluble polymer (poly(ethylene glycol), PEG) and an inorganic salt ((NH4)2SO4), in the presence of halide ions. In the absence of a suitable extracting
LAURA BULGARIU, DUMITRU BULGARIU
doaj +3 more sources

