Determination of the parameters of thermodynamic stability constants of bromide complexes of rare earth metals for modeling the optimal regimes of hydrometallurgical extraction [PDF]
Determination of the thermodynamic parameters of complex compounds of rare earth metals in aqueous solutions is of considerable interest for understanding the hydrometallurgical processes associated with the extraction and separation of yttrium and ...
Fialkovsky Igor Sergeevich +3 more
doaj +3 more sources
18-Crown-6 and Dibenzo-18-crown-6 Assisted Extraction of Cesium from Water into Room Temperature Ionic Liquids and Its Correlation with Stability Constants for Cesium Complexes [PDF]
The pH-profiles of the extraction of Cs+ into four conventional (1-butyl-3-methylimidazolium hexafluorophosphate and bis[trifluoromethyl)sulphonyl]imides of 1-butyl-3-methylimidazolium, 1-hexyl-3-methylimidazolium, and 1-(2-ethylhexyl)-3 ...
Igor Vladimirovich Pletnev +6 more
doaj +5 more sources
Distribution of micro-amounts of europium in the two-phase water-HCl-nitrobenzene-N,N'-dimethyl-N,N'-diphenyl-2,6-dipicolinamide-hydrogen dicarbollylcobaltate extraction system [PDF]
Extraction of micro-amounts of europium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of N,N'-dimethyl- -N,N'-diphenyl-2,6-dipicolinamide (MePhDPA, L) was investigated.
Makrlík Emanuel +4 more
doaj +5 more sources
Solvent extraction of trivalent europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate and tetraisopropyl[oxybis(2,1-ethanediyliminocarbonyl)]-bisphosphoramidate [PDF]
Solvent extraction of micro-amounts of Eu3+ and Am3+ from water into nitrobenzene by means of a mixture of hydrogen dicarbollylcobaltate (H+B-) and tetraisopropyl[oxybis(2,1-ethanediyliminocarbonyl)]-bisphosphoramidate (L) was studied.
Makrlík Emanuel +3 more
doaj +3 more sources
Determination of the Stability Constants of Crown Ether Complexes With Protonated Amines by Solvent Extraction [PDF]
Abstract Stability constants of crown ether complexes with protonated primary amines were determined by the solvent extraction method. Stability constants between protonated amines(AH+) and 18-crown-6(L), logKAHL, were found to be 0.4, 0.15, 0.1, −0.05, and −0.1 for protonated methylamine, ethylamine, propylamine, butylamine, and iso ...
Hideyuki Noguchi, Masaki Yoshio
exaly +2 more sources
Activation of the Aromatic Core of 3,3'-(Pyridine-2,6-diylbis(1H-1,2,3-triazole-4,1-diyl))bis(propan-1-ol)-Effects on Extraction Performance, Stability Constants, and Basicity. [PDF]
Abstract The “CHON” compatible water-soluble ligand 3,3′-(pyridine-2,6-diylbis(1H-1,2,3-triazole-4,1-diyl))bis(propan-1-ol) (PTD) has shown promise for selectively stripping actinide ions from an organic phase containing both actinide and lanthanide ions, by preferential complexation of the former. Aiming at improving its complexation
Weßling P +11 more
europepmc +6 more sources
This study optimized the extraction of asiaticoside and asiatic acid from Centella asiatica using an ultrasonic-assisted extraction method. The research focused on ethanol concentration, extraction temperature, and extraction duration to maximize yield efficiency.
Teerin Chysirichote
exaly +3 more sources
Solvent extraction of Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, UO22+, Mn2+, Co2+ and Ni2+ into nitrobenzene using strontium dicarbol-lylcobaltate and tetra-tert-butyl p-tert-butylcalix[4]arene tetraacetate [PDF]
The exchange extraction constants corresponding to the general equilibrium M2+(aq) + SrL2+(nb) D ML2+ (nb) + Sr2+ (aq) occurring in the two-phase water–nitrobenzene system (M2+ = Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, UO22+, Mn2+, Co2+ or Ni2+; L = tetra ...
E. MAKRLÍK +3 more
doaj +3 more sources
Studies on the separation of some transition metals using trialkylimidazole as selective extractant [PDF]
The possibility of Cu(II) ion separation from an equimolar Cu-Cd-Zn tertiary mixture by solvent extraction was investigated. The process was based on the use of 1,2,4-trimethylimidazole (TMI) and 1- decyl-2,4-dimethylimidazole (DDMI) as extractant ...
Radzyminska-Lenarcik Elzbieta +1 more
doaj +2 more sources
Calcium ionophore I as very effective extraction agent for trivalent europium and americium [PDF]
The solvent extraction of microamounts of Eu3+ and Am3+ from water into nitrobenzene by means of a mixture of hydrogen dicarbollylcobaltate (H+B-) and calcium ionophore I (marked as the ligand L) was investigated. The equilibrium data have been explained
Makrlík Emanuel, Vaňura Petr
doaj +1 more source

