Results 111 to 120 of about 348,558 (295)

Quercetin•Zirconium Metal Complexes: Insights from Femto to Millisecond Photobehavior

open access: yesChemistry – A European Journal, EarlyView.
The switching off of excited‐state intramolecular proton transfer (ESIPT), followed by the switching on of ligand‐to‐metal charge transfer (LMCT) processes in quercetin (QRT)•Zr complexes, is crucial for generating Zr‐bound QRT radicals that exhibit significantly shorter lifetimes compared to free QRT radicals.
Subhrakant Jena   +3 more
wiley   +1 more source

Pyrimidine‐Based Four‐Coordinate O^N^O Boron Complexes: Synthesis, Photophysical and Theoretical Studies, and TADF‐Based OLED Devices

open access: yesChemistry – A European Journal, EarlyView.
This article describes the synthesis, along with the full photophysical and computational characterization, of a series of push‐pull boron complexes comprising a sterically hindered donor connected to a pyrimidine‐based O^N^O boron chelate. Incorporation of the dimethylacridan derivative into an organic light‐emitting diode led to the observation of ...
Clément Diguet   +11 more
wiley   +1 more source

A General Approach to Dropout in Quantum Neural Networks

open access: yesAdvanced Quantum Technologies, EarlyView., 2023
Randomly dropping artificial neurons and all their connections in the training phase reduces overfitting issues in classical neural networks, thus improving performances on previously unseen data. The authors introduce different dropout strategies applied to quantum neural networks, learning models based on parametrized quantum circuits.
Francesco Scala   +3 more
wiley   +1 more source

Exploring the Impact of Phenanthroline‐Based Glycoconjugated Ru(II) Polypyridyl Photosensitizers on Metastasis‐Related Processes

open access: yesChemistry – A European Journal, EarlyView.
A novel family of water‐soluble, nontoxic, and phosphorescent N‐glycosylated Ru(II) phenanthroline‐based complexes are reported. They exhibit photoselectivity indexes ranging from 10 to 44 in PC‐3 cells, while impacting cell migration and resistance to detachment after irradiation with blue light.
Elena de la Torre‐Rubio   +5 more
wiley   +1 more source

Benefits of Open Quantum Systems for Quantum Machine Learning

open access: yesAdvanced Quantum Technologies, EarlyView., 2023
Quantum machine learning (QML), poised to transform data processing, faces challenges from environmental noise and dissipation. While traditional efforts seek to combat these hindrances, this perspective proposes harnessing them for potential advantages. Surprisingly, under certain conditions, noise and dissipation can benefit QML.
María Laura Olivera‐Atencio   +2 more
wiley   +1 more source

Didáctica para enseñar a jugar en Educación Física desde una perspectiva emancipadora [PDF]

open access: yes, 2019
La presente investigación ha tenido como propósito contribuir a la construcción de una didáctica que enseñe a jugar lúdicamente en el contexto socializador de las clases de Educación Física. El estudio según la búsqueda de conocimiento ha sido de tipo aplicado y temporalmente sincrónico, habiéndose desarrollado un diseño sustentado en la metodología ...
openaire  

Boost of Chiroptical Responses Through the Enhancement of Electron Transition Dipole Moment

open access: yesChemistry – A European Journal, EarlyView.
Chiral spirobifluorene systems are peripherally π‐extended via Knoevenagel condensation to boost their electric transition dipole moments (ETDM). A direct ETDM–g‐factor correlation is established through ECD and TD‐DFT analyses. This strategy allows precise control of exciton coupling and chiroptical amplification in rigid π‐conjugated scaffolds ...
Iván Gómez‐Oya   +4 more
wiley   +1 more source

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