Ground‐ and Excited‐State Mixed Valency in a 4,4′‐Bipyridine‐Bridged Bimetallic Di‐Ruthenium Complex
Photoinduced mixed‐valence interactions across a 4,4′‐bpy bridge were studied. MLCT excited states in the bimetallic complex are longer‐lived than in the monometallic reference, thanks to metal–metal electronic coupling and hole delocalization, but are still shorter than the nanosecond timescale relevant for diffusional reactivity.
Ivana Ramírez‐Wierzbicki +3 more
wiley +1 more source
Molecular QCA: a write-in system based on electric fields [PDF]
Abrardi, C. +4 more
core +1 more source
A modular library of structurally robust palladacyclopentadienyl Pd(II) complexes bearing achiral and chiral diphosphines was developed, revealing a strong influence of diphosphine design and ligand chirality on cytotoxicity and selectivity against ovarian cancer cells, including platinum‐resistant models.
Stefania Mautone +7 more
wiley +1 more source
Effect of oxygenated ferrocene derivatives on soot formation and nanoparticle emissions in <i>n</i>-heptane diffusion flames. [PDF]
C V A, Mitra R, Thajudeen T, Ambekar A.
europepmc +1 more source
Near‐infrared fluorescent pH indicators based on perylenediimide were constructed in a modular receptor–spacer–fluorophore–spacer–receptor format with heterocyclic amino moieties at the bay positions. Counterintuitively, the dibrominated intermediate with two heavy atoms is more emissive than the heterocyclic compounds.
Luke Camenzuli +4 more
wiley +1 more source
Length-dependent quantum interference and high thermoelectric response ferrocene-modified OPE wires. [PDF]
Al-Jobory AA +3 more
europepmc +1 more source
Bridging the gap. Beyond deck functionalization, the ethylene bridges of [2.2]paracyclophanes offer a largely unexploited reactivity landscape. This review showcases strategies to functionalize these bridges and leverage them to build novel cyclophane architectures.
Rongyu Sun +3 more
wiley +1 more source
Comparative Evaluation of Electrochemical and Fluorescent Readouts for Immunomagnetically Captured Waterborne Pathogens Using a Biochip with Bifunctional Magnetic Nanoparticles. [PDF]
Gunasekaran D +3 more
europepmc +1 more source
Organic Photodetectors and Sensors for Low‐Light and Infrared Applications
This mini review highlights recent advances in organic photodetectors and sensors for low‐light and infrared applications, emphasizing molecular design, device architectures, and interface engineering that improve charge transport, detectivity, speed, and spectral selectivity.
Swarup Biswas, Hyeok Kim
wiley +1 more source
Absolute Calibration for Cyclic Voltammetry from the Solution-Phase Ionisation of Ferrocene. [PDF]
Baikie TK +5 more
europepmc +1 more source

