Results 151 to 160 of about 54,509 (296)

Ground‐ and Excited‐State Mixed Valency in a 4,4′‐Bipyridine‐Bridged Bimetallic Di‐Ruthenium Complex

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Photoinduced mixed‐valence interactions across a 4,4′‐bpy bridge were studied. MLCT excited states in the bimetallic complex are longer‐lived than in the monometallic reference, thanks to metal–metal electronic coupling and hole delocalization, but are still shorter than the nanosecond timescale relevant for diffusional reactivity.
Ivana Ramírez‐Wierzbicki   +3 more
wiley   +1 more source

Molecular QCA: a write-in system based on electric fields [PDF]

open access: yes, 2011
Abrardi, C.   +4 more
core   +1 more source

Stereochemical Modulation of Palladacyclopentadienyl Complexes Bearing Diphosphine Ligands: A Key to Enhanced DNA Interaction and Anticancer Activity

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
A modular library of structurally robust palladacyclopentadienyl Pd(II) complexes bearing achiral and chiral diphosphines was developed, revealing a strong influence of diphosphine design and ligand chirality on cytotoxicity and selectivity against ovarian cancer cells, including platinum‐resistant models.
Stefania Mautone   +7 more
wiley   +1 more source

On the Planarity of Heterocyclic Bay‐Substituted Perylenediimides: Insight into the Fluorescent Photoinduced Electron Transfer Sensing Framework

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Near‐infrared fluorescent pH indicators based on perylenediimide were constructed in a modular receptor–spacer–fluorophore–spacer–receptor format with heterocyclic amino moieties at the bay positions. Counterintuitively, the dibrominated intermediate with two heavy atoms is more emissive than the heterocyclic compounds.
Luke Camenzuli   +4 more
wiley   +1 more source

Unlocking the Functionalization and Reactivity of Ethylene Bridges in [2.2]Paracyclophanes: Strategies and Challenges

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Bridging the gap. Beyond deck functionalization, the ethylene bridges of [2.2]paracyclophanes offer a largely unexploited reactivity landscape. This review showcases strategies to functionalize these bridges and leverage them to build novel cyclophane architectures.
Rongyu Sun   +3 more
wiley   +1 more source

Organic Photodetectors and Sensors for Low‐Light and Infrared Applications

open access: yesElectron, EarlyView.
This mini review highlights recent advances in organic photodetectors and sensors for low‐light and infrared applications, emphasizing molecular design, device architectures, and interface engineering that improve charge transport, detectivity, speed, and spectral selectivity.
Swarup Biswas, Hyeok Kim
wiley   +1 more source

Absolute Calibration for Cyclic Voltammetry from the Solution-Phase Ionisation of Ferrocene. [PDF]

open access: yesACS Electrochem
Baikie TK   +5 more
europepmc   +1 more source

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