Results 251 to 260 of about 818,900 (309)

Homoleptic and Heteroleptic Borylones L1‐B(Ph)‐L2

open access: yesAngewandte Chemie, EarlyView.
Density functional theory and CCSD(T) calculations reveal that homoleptic and heteroleptic borylones L1–B(Ph)–L2 are thermodynamically accessible. Remarkably, the homoleptic borylones B(Ph)(N2)2 and B(Ph)(SPh2)2 exhibit higher bond dissociation energies than the related carbones.
Qin Ma   +4 more
wiley   +1 more source

Tandem Reactivity of Metal−Carbon and Carbon−Silicon Bonds in Mononuclear α‐Silyl Organolithium or Organosodium Complexes Towards CO, CO2 and Heteroallenes

open access: yesAngewandte Chemie, EarlyView.
Anionic α‐silyl alkyl is one of the most used organometallic building blocks and funtional groups. Traditionally, the C─Si bond in these complexes is considered as inert. In this work, we report a series of reactions between mononuclear organo‐lithium and ‐sodium complexes with CO, CO2, or heteroallenes.
Xiao Yang   +8 more
wiley   +1 more source

One‐Step Radical‐Intensified Selective Etching (RISE) Strategy for High‐Yield Synthesis of Monolayer MXene with Tailored Nanoholes

open access: yesAngewandte Chemie, EarlyView.
Radical‐intensified selective etching (RISE) delivers monolayer MXenes with >80% yield in just 3 h etching process. Controlled ·OH dosage enables one‐step access to holey MXenes with abundant nanopores or defect‐lean flakes. This mild, safe strategy couple ultrafast kinetics with structural tunability, advancing precision design of MXene architectures.
Chenxu Liu   +8 more
wiley   +1 more source

Patient Journey for Triple-Negative Breast Cancer: Optimal Care Pathways vs. Reality of Care in Italian Breast Units. [PDF]

open access: yesCurr Oncol
La Verde N   +13 more
europepmc   +1 more source

Awareness and best practices in using ketogenic therapy to treat serious mental illness: a modified Delphi consensus. [PDF]

open access: yesFront Nutr
Ede G   +7 more
europepmc   +1 more source

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