Results 141 to 150 of about 82,480 (289)

Entropy‐Controlled Exsolution of Highly Dispersed Nickel‐Based Active Metals From Spinel Oxide via Optimizing Metal‐Support Interaction for Dry Reforming of Methane

open access: yesCarbon Energy, EarlyView.
The incorporation of transition‐metal elements into spinel oxides results in enhanced configurational entropy and increased metal‐support interaction, which continuously modulate the exsolution of nickel‐based active metal. The highly dispersed nickel‐based metal catalyst, formed through the entropy‐controlled strategy, demonstrates remarkable activity
Yuxuan Meng   +10 more
wiley   +1 more source

Precision Catalysis in Dehydrogenation of Liquid Organic Hydrogen Carriers: Molecular Structure‐Geometry‐Electronic Interplay for Enhanced Hydrogen Evolution

open access: yesCarbon Energy, EarlyView.
Atomic‐scale design principles for LOHC dehydrogenation: Tailoring geometric and electronic effects in metal catalysts to bridge the molecular structure of LOHC and dehydrogenation performance. ABSTRACT The advancement of hydrogen‐based energy systems necessitates innovative solutions for safe, efficient hydrogen storage and transportation.
Yongxiao Tuo   +8 more
wiley   +1 more source

Adsorption of pentachlorophenol onto activated carbon in a fixed bed : a thesis presented in partial fulfilment of the requirements for the degree of Master of Technology in Environmental Engineering at Massey University [PDF]

open access: yes, 1995
The adsorption of pentachlorophenol (PCP) from water onto granular activated carbon (GAC) was studied. Equilibrium and kinetic behaviour was studied, and the results used to predict fixed bed adsorber behaviour.
Slaney, Andrew James
core  

Boosting C=O Bond Scissoring Over a Pyridinic Nitrogen‐Modified Cu–MoC Interface for High‐Efficiency CO2 Hydrogenation to CO

open access: yesCarbon Energy, EarlyView.
ABSTRACT Reverse water‐gas shift (RWGS) reaction‐aided sustainable CO2 conversion has emerged as one promising and effective approach for simultaneously mitigating climate change and solidifying energy security. Molybdenum carbide‐based catalysts demonstrate excellent selectivity for sustainably transforming CO2 into CO product, but harsh carburization
Haiquan Liao   +13 more
wiley   +1 more source

Two‐Step Synthesis of a Chiral Fluorinated Alcohol With Silica‐Supported Enzyme RrADH in Batch and Continuous Flow Mode

open access: yesChemistry – A European Journal, EarlyView.
A two‐step process was transferred from batch to flow mode for the synthesis of (R)‐2‐fluoro‐1‐phenylethanol as a benchmark, consisting of a decarboxylative fluorination in aqueous media, followed by an enantioselective biocatalytic reduction of the prochiral intermediate with RrADH immobilized on silica supraparticles.
Egzon Cermjani   +7 more
wiley   +1 more source

Nonlinear Active Site Dynamic Behavior Over In Situ Generated Working Zeolites

open access: yesChemie Ingenieur Technik, EarlyView.
The methoxymethyl mechanism over α, β, and γ site ensembles and the dynamic site‐interconversion mechanism reduce the induction period of propylene formation. The methoxymethyl mechanism acts on site ensemble α generating surface methoxy species (SMS), which, through the dynamic site‐interconversion mechanism, lead to SMS on site ensembles β and γ that
Toyin Omojola
wiley   +1 more source

In Situ Methanation on Mars: A Process Concept Study on the Impact of H2/CO2 and Recycle Ratio

open access: yesChemie Ingenieur Technik, EarlyView.
The rocket propellant methane can be produced on Mars by in situ resource utilization. The H2/CO2 ratio is decisive, and excess H2 is favored for providing sufficient propellant purity. The operation mode—with or without recycling of unreacted reactants—depends on the resource availability of the selected landing site. Abstract For return missions from
Franz Braun   +4 more
wiley   +1 more source

Integration of High‐p, Low‐T CO2 Electrolysis with Pressure Swing Adsorption Purification

open access: yesChemie Ingenieur Technik, EarlyView.
We evaluate a high‐p low‐T CO2 electrolysis (LTCE) cell with a pressure swing adsorption (PSA) to compare cascade vs. recycle operation. Although a cascade yields high CO selectivity but limited yield, a full recycle achieves near‐quantitative CO production, highlighting gas recycling as essential for LTCE/PSA systems.
Martin Peters   +5 more
wiley   +1 more source

Integrated and closed‐loop biorefinery strategies for efficient waste valorization and biofuel production

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Advancements in biofuel production technologies are essential for reducing global dependence on fossil fuels and addressing their overexploitation. Many valuable components of biomass, such as cellulose, hemicellulose, and lignin, remain underused in traditional biorefineries, which typically rely on a single feedstock to produce a primary ...
Marcos Paulo Patta Granado   +5 more
wiley   +1 more source

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