Results 141 to 150 of about 76,488 (262)
Low‐Temperature Initiation Enhances HCN and NH3 Formation From Methane and NO Over Pt/Al2O3
Chemistry – A European Journal, EarlyView.Hydrogen cyanide (HCN) was formed from CH4 and NO over Pt/Al2O3 at low temperatures. Increasing NO concentration and optimizing reaction‐start conditions significantly enhanced HCN yield. In situ FTIR and DXAFS measurements revealed that dynamically balancing Pt‑CO and Pt‑CN surface species, particularly their desorption under temperature‑swing ...
Emika Yamashita +3 more
wiley +1 more source
Axial Changes of Catalyst Structure and Temperature in a Fixed-Bed Microreactor During Noble Metal Catalysed Partial Oxidation of Methane [PDF]
, 2018 The catalytic partial oxidation of methane (CPO) over flame-made 2.5%Rh-2.5%Pt/Al2O3 and 2.5%Rh/Al2O3 in 6%CH4/3%O2/He shows the potential of in situ studies using miniaturized fixed-bed reactors, the importance of spatially resolved studies and its ...
Baiker, Alfons +5 more
core
The Canadian Journal of Chemical Engineering, EarlyView.Abstract Synthetic jet fuel containing non‐petroleum‐derived kerosene can be produced from synthetic kerosene obtained through processes that include a hydroprocessing step. The potential use of non‐sulphided (reduced) nickel supported on alumina (Ni/Al2O3) was evaluated as an alternative to sulphided catalysts to saturate alkenes in sulphur‐free ...
Garima Chauhan +3 more
wiley +1 more source
Characterization of coal products from high temperature processing of Usibelli low-rank coals [PDF]
, 1991 This research project was conducted in association with Gilbert/Commonwealth Inc. as part of an overall techno-economic assessment of high temperature drying of low-rank coals. This report discusses the characteristics of the dried/pyrolyzed products of
Li, YuFu +3 more
core
A study of Ni‐Co/CeO2 catalyst derived from metal–organic framework for dry reforming of methane
The Canadian Journal of Chemical Engineering, EarlyView.Abstract The efficacy of cobalt‐doped, MOF‐derived catalysts for dry reforming of methane (DRM) was examined. The focus was on the influence of varying nickel and cobalt molar ratios on catalytic performance. Three catalysts with Ni:Co ratios of 1:1, 1:0.5, and 0.5:1, were synthesized and tested with cerium oxide as a constant support. The DRM reaction
Ruth D. Alli, Nader Mahinpey
wiley +1 more source
The Canadian Journal of Chemical Engineering, EarlyView.Abstract Several authors have reported the disconnection between the skills, abilities, and attitudes of graduates from STEM careers with the current needs of the labour market. In science and engineering fields, research has found the need for interdisciplinary approaches that encourage meaningful learning.
Úrsula Manríquez‐Tolsá +7 more
wiley +1 more source
Modelling of continuous low‐temperature emulsion co‐polymerization in 3D‐printed reactor
The Canadian Journal of Chemical Engineering, EarlyView.A kinetic model for the emulsion copolymerization of butyl acrylate/styrene at low temperatures is proposed and validated against experiments with a redox initiator system. The model was successfully transferred to a 3D‐printed tubular reactor and conversions of more than 80% and small particles sizes below 40 nm were observed.
Ferel Issa +2 more
wiley +1 more source
Revisiting the synthesis of dimethyl carbonate from methanol and carbon dioxide
The Canadian Journal of Chemical Engineering, EarlyView.Abstract The process for producing dimethyl carbonate (DMC) from carbon dioxide (CO2) and methanol is explored in this article. It provides an overview of the thermodynamics involved in DMC synthesis, discussing the challenges and potential solutions. The article highlights the reported use of catalysts and dehydrating agents to improve DMC yield and ...
Diego Alexander Santos Araque +3 more
wiley +1 more source
Beyond hydrogen: Process design of a biogas steam reformer for Fischer–Tropsch synthesis
The Canadian Journal of Chemical Engineering, EarlyView.The effect of pressure and steam to carbon ratio on carbon conversion. Abstract We present an analysis of a pilot‐scale multi‐tubular biogas steam reforming reactor, part of a sustainable aviation fuel (SAF) development project in Brazil. The novelty of this work is the application of a new, validated power law kinetic model, specifically developed for
Rafael Belo Duarte +3 more
wiley +1 more source
The Canadian Journal of Chemical Engineering, EarlyView.Comparison of PSA and amine‐based absorption for syngas purification shows that PSA offers lower energy intensity, global warming potential, and minimum selling price, making it a more sustainable option. However, absorption achieves higher syngas purity. A GREENSCOPE‐based multi‐criteria assessment guides optimal process selection.
Magno Fonseca Santos +2 more
wiley +1 more source