Results 151 to 160 of about 3,794,002 (328)

Iridium Complexes of a Triazole‐Derived Pincer Ligand: Synthesis, Reactivity, and Transfer Dehydrogenation Catalysis

open access: yesChemistry – A European Journal, EarlyView.
Ir pincer complexes bearing a triazole architecture in the pincer backbone and O‐ancillary chelating ligands are presented. These were employed in the catalytic transfer dehydrogenation of alkanes as well as of saturated heterocycles. Reactivity of these complexes with silver salts and Lewis acids produced various cationic iridium complexes.
Jesvita Cardozo   +5 more
wiley   +1 more source

Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives

open access: yesChemistry – A European Journal, EarlyView.
Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch   +3 more
wiley   +1 more source

Catalyst‐Free Cyanation of Arenes by Acetonitrile in a Plasma–Liquid Microreactor

open access: yesChemistry – A European Journal, EarlyView.
An original approach of arylnitrile synthesis was developed by generating an argon plasma in contact with solutions of arene in acetonitrile within a gas‐liquid microreactor. Plasma activation of acetonitrile generated cyano radicals, enabling a catalyst‐free C‐H cyanation of arenes.
Pierre Dedieu   +4 more
wiley   +1 more source

The Filament Extension Atomization Process for Powder Production of Elastic Fluids

open access: yesChemie Ingenieur Technik, EarlyView.
Filament extension atomization is a promising technique for spraying a wide range of materials, enabling narrow droplet size distributions. This study examines the behavior of various fluids and suspensions to define application limits and identify optimal operating conditions.
Moritz Neukötter   +4 more
wiley   +1 more source

Influence of Particle Size, Moisture, and Cloud Density on Wood Dust Ignition

open access: yesChemie Ingenieur Technik, EarlyView.
The ignition and combustion of particle clouds are strongly affected by particle interactions. This study uses spectroscopy to examine effects of particle size, water content, and cloud density. Results show ignition delay rises with larger size and density, whereas combustion duration depends mainly on water and density due to moisture‐driven ...
Matteo Giesen   +2 more
wiley   +1 more source

Global and Detailed Calculation of Tube Wall Temperature in a Process Furnace Steam Superheater

open access: yesChemie Ingenieur Technik, EarlyView.
This study presents a comparison between an iterative global model and multiple approaches to a new non‐iterative model with the purpose of predicting tube wall temperature of a superheater. The results show that the non‐iterative method achieves sufficient accuracy while improving the prediction of local temperature distribution and better ...
Anežka Michálková, Zdeněk Jegla
wiley   +1 more source

Hydroprocessing of synthetic kerosene over a non‐sulphided Ni/Al2O3 catalyst: Impact of alcohols and ketones on alkene conversion

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Synthetic jet fuel containing non‐petroleum‐derived kerosene can be produced from synthetic kerosene obtained through processes that include a hydroprocessing step. The potential use of non‐sulphided (reduced) nickel supported on alumina (Ni/Al2O3) was evaluated as an alternative to sulphided catalysts to saturate alkenes in sulphur‐free ...
Garima Chauhan   +3 more
wiley   +1 more source

Home - About - Disclaimer - Privacy