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Investigating the Structural Factors Influencing the Magnetic Interaction between Individual Copper Spins in the CuCu4 Metallacrown Complex, from Its Bulk Form to Its Adsorption on Au(111)

open access: yesAdvanced Materials Interfaces, EarlyView.
The Cu(II)[12‐MCCu(II)N(Shi)‐4] metallacrown complex (CuCu4) is studied to examine how geometric transformations affect magnetic coupling between copper spins by using ultraviolet photoemission spectroscopy and DFT calculations for the bulk phase and CuCu4 adsorbed on Au(111). While adsorption minimally affects tDOS, exchange coupling constants between
Ariyan Tavakoli   +11 more
wiley   +1 more source

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