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Fluctuation theorem for nonequilibrium reactions

The Journal of Chemical Physics, 2004
A fluctuation theorem is derived for stochastic nonequilibrium reactions ruled by the chemical master equation. The theorem is expressed in terms of the generating and large-deviation functions characterizing the fluctuations of a quantity which measures the loss of detailed balance out of thermodynamic equilibrium.
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The fluctuation theorem. (Shot effect)

Mathematical Proceedings of the Cambridge Philosophical Society, 1939
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