Results 81 to 90 of about 35,154 (267)

(Sila)Difluoromethylation of Fluorenyllithium with CF3H and CF3TMS

open access: yesSynOpen, 2018
Difluoromethylation of the C9-H site of the fluorene ring using lithium base and fluoroform (CF3H), which is one of the most cost-effective difluoromethylating reagents, is attained to give difluoromethylated fluorenes with an all-carbon quaternary ...
Kenichi Maruyama   +2 more
doaj   +1 more source

Synthesis and characterization of a novel quaternary copolymerized thermoplastic copolyimide with excellent heat resistance, thermoplasticity, and solubility

open access: yeseXPRESS Polymer Letters, 2020
A series of novel quaternary copolymerized thermoplastic polyimides were successfully prepared with asymmetric diahydride: 3,4′-oxydiphthalic anhydride (a-ODPA) and symmetric anhydride: 4,4′-oxydiphthalicanhydride (s-ODPA), 9,9′-bis(4-aminophenyl ...
X. W. Cao, C. Wei, G. J. He, X. Liu
doaj   +1 more source

Exciton Dissociation Dynamics in Model Donor-Acceptor Polymer Heterojunctions: I. Energetics and Spectra

open access: yes, 2005
In this paper we consider the essential electronic excited states in parallel chains of semiconducting polymers that are currently being explored for photovoltaic and light-emitting diode applications.
Eric R. Bittner   +3 more
core   +1 more source

9-Chloromethyl-9-[(9H-fluoren-9-yl)methyl]-9H-fluorene [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2008
In the title compound, C(28)H(21)Cl, the dihedral angle between the two fluorene ring systems is 71.97 (4)°. There is an intra-molecular C-H⋯Cl hydrogen bond. In the crystal structure, the centroid-to-centroid distance between stacked fluorene ring systems is ca 4.22 Å, which indicates that there are no π-π stacking inter-actions between them.
Shen, Qun   +3 more
openaire   +2 more sources

Isolation und Reaktivtät eines quadratisch‐planaren Trisamidosilans

open access: yesAngewandte Chemie, EarlyView.
Wir berichten über die Synthese und umfassende Charakterisierung eines quadratisch‐planaren Si(+IV)‐Hydrids, das von einem unsymmetrischen, trianionischen und dearomatisierten N,N,N‐Pincerliganden stabilisiert wird. Dieses System ermöglicht eine Element–Liganden‐kooperative Reaktivität als Alternative zur siliciumzentrierten Redoxchemie und erweitert ...
David M. J. Krengel   +5 more
wiley   +1 more source

The electronic structure of free radical 9-fluorenyl within the framework of QTAIM

open access: yesФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов
The paper presents the results of studying the influence of free valence on the electronic structure of 9-fuorenyl radical in comparison with the fluorene molecule.
E.M. Chernova   +2 more
doaj   +1 more source

Transformation of Substituted Fluorenes and Fluorene Analogs by Pseudomonas sp. Strain F274 [PDF]

open access: yesApplied and Environmental Microbiology, 1995
Pseudomonas sp. strain F274, previously shown to catabolize fluorene via fluorenone and its angular dioxygenation, 2(prm1),3(prm1)-dihydroxy-2-carboxybiphenyl, phthalate, and protocatechuate, was examined for its ability to transform substituted fluorenes and S- and N-heterocyclic analogs.
M, Grifoll, S A, Selifonov, P J, Chapman
openaire   +2 more sources

One-Dimensional Fluorene-Based Co(II) Phosphonate Co(H2O)2PO3C–C12H9·H2O: Structure and Magnetism

open access: yesInorganics, 2018
A new Co(II) phosphonate, Co(H2O)2PO3C–C12H9·H2O, has been synthesized under hydrothermal conditions. The monoclinic P21/c structure of this organic–inorganic hybrid consists of isolated perovskite-type chains of corner-shared CoO4(H2O)
Clarisse Bloyet   +7 more
doaj   +1 more source

Polyfluoralkylierte zellpenetrierende Peptid‐Additive verbessern die intrazelluläre Proteinaufnahme durch eine anhaltende und monomere Lipidinteraktion

open access: yesAngewandte Chemie, EarlyView.
Wir berichten, dass nicht‐zytotoxische, polyfluoralkylierte zellpenetrierende Peptide (CPPs) als CPP‐Additive die intrazelluläre Proteinaufnahme signifikant verbessern, indem sie die Membranverweildauer der CPP‐Additive erhöhen. Durch die Kombination von biophysikalischen Experimenten und Molekulardynamiksimulationen zeigen wir zudem, dass die ...
Sarah Hansen   +10 more
wiley   +1 more source

High Fluorescent Porphyrin-PAMAM-Fluorene Dendrimers

open access: yesMolecules, 2015
Two new classes of dendrimers bearing 8 and 32 fluorene donor groups have been synthesized. The first and second generations of these porphyrin-PAMAM-fluorene dendrimers were characterized by 1H-NMR, 13C-NMR, FTIR, UV-vis spectroscopy, elemental analyses
Karla I. Garfias-Gonzalez   +6 more
doaj   +1 more source

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