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Fluorinated terpenoids and their fluorine-containing derivatives. [PDF]

open access: yesRSC Adv
Synthetic methods for the fluorination of terpenoids have enabled the development of fluorinated terpenoids as important pharmaceuticals.
Huda MB   +3 more
europepmc   +4 more sources

Fluorine‐Doping of Mesoporous TiO2 Enables Efficient Defect Passivation for High‐Efficiency and Stable Perovskite Solar Cells [PDF]

open access: yesAdvanced Science
Mesoporous titanium dioxide (m‐TiO2) is widely used as an electron transport layer (ETL) in perovskite solar cells (PSCs), but its large surface area introduces oxygen‐vacancy‐related trap states that accelerate nonradiative recombination, particularly ...
Hye W. Chun   +12 more
doaj   +2 more sources

An assessment of the potential for leaching of per- and polyfluoroalkyl substances from fluorinated and non-fluorinated high-density polyethylene containers

open access: yesEnvironmental Advances, 2022
Per- and polyfluoroalkyl substances (PFAS) have garnered world-wide attention over the last two decades due to their extreme environmental persistence and potential adverse health effects. Research is ongoing as to where, and in what quantities, PFAS can
Rock J. Vitale   +2 more
doaj   +1 more source

Novel Passivation Approach of InAs/GaSb Superlattice for Mid-Short Wavelength Dual-Color Infrared Detector [PDF]

open access: yesHangkong bingqi, 2021
For higher surface state density of InAs/GaSb type II superlattice materials, it is easy to form conductive oxide layer on the material surface. The first problem to be solved is passivation in the process of preparing infrared devices with InAs/GaSb ...
Zhang Lixue, Lu Xing, Zhu Xubo, Yao Guansheng
doaj   +1 more source

Bipolar Electrochemical Fluorination of Triphenylmethane and Bis(phenylthio)diphenylmethane Derivatives in a U-shaped Cell

open access: yesElectrochemistry, 2021
Electrochemical fluorination of triphenylmethane derivatives and bis(phenylthio)diphenylmethane derivatives by using a split bipolar electrode is described.
Naoki SHIDA   +9 more
doaj   +1 more source

Inter- and Intra-Molecular Organocatalysis of SN2 Fluorination by Crown Ether: Kinetics and Quantum Chemical Analysis

open access: yesMolecules, 2021
We present the intra- and inter-molecular organocatalysis of SN2 fluorination using CsF by crown ether to estimate the efficacy of the promoter and to elucidate the reaction mechanism.
Young-Ho Oh   +6 more
doaj   +1 more source

Thermodynamics and Kinetics Research of the Fluorination Process of the Concentrate Rutile

open access: yesMetals, 2021
The growth in the production of titanium metal and its compounds leads to an increase in the amount of toxic waste. As a result, at the legislative level, emissions of such wastes are limited, which leads to a drop in the production of titanium ...
Vladimir A. Karelin   +5 more
doaj   +1 more source

Drug Discovery Based on Fluorine-Containing Glycomimetics

open access: yesMolecules, 2023
Glycomimetics, which are synthetic molecules designed to mimic the structures and functions of natural carbohydrates, have been developed to overcome the limitations associated with natural carbohydrates.
Xingxing Wei   +4 more
doaj   +1 more source

Harnessing Ionic Interactions and Hydrogen Bonding for Nucleophilic Fluorination

open access: yesMolecules, 2020
We review recent works for nucleophilic fluorination of organic compounds in which the Coulombic interactions between ionic species and/or hydrogen bonding affect the outcome of the reaction.
Young-Ho Oh   +4 more
doaj   +1 more source

Introduction of Fluorine and Fluorine‐Containing Functional Groups [PDF]

open access: yesAngewandte Chemie International Edition, 2013
AbstractOver the past decade, the most significant, conceptual advances in the field of fluorination were enabled most prominently by organo‐ and transition‐metal catalysis. The most challenging transformation remains the formation of the parent CF bond, primarily as a consequence of the high hydration energy of fluoride, strong metal—fluorine bonds ...
Liang, Theresa   +2 more
openaire   +5 more sources

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