Results 101 to 110 of about 22,231 (296)

Organic Materials of Tomorrow: Horizons of Artificial Intelligence

Advanced Materials, EarlyView.
This review examines machine learning techniques accelerating the discovery of organic semiconductors by linking molecular structure to properties. Key methods include graph neural networks, generative models, and active learning. Applications to organic photovoltaics demonstrate practical impact.
Harold Mena, J. Terence Blaskovits, Kun‐Han Lin, Denis Andrienko   +3 more
wiley   +1 more source

Single and double stereoselective fluorination of (E)-allylsilanes

Beilstein Journal of Organic Chemistry, 2007
Acyclic allylic monofluorides were prepared by electrophilic fluorination of branched (E)-allylsilanes with Selectfluor. These reactions proceeded with efficient transfer of chirality from the silylated to the fluorinated stereocentre.
Marcin Sawicki, Angela Kwok, Matthew Tredwell, Véronique Gouverneur   +3 more
doaj   +1 more source

Ionizable Lipid‐Dependent Optimization of Steroid Lipid Nanoparticles With Tunable Immunomodulatory Properties

Advanced Materials, EarlyView.
A novel engineering strategy that establishes material design principles for incorporating anti‐inflammatory steroids into lipid nanoparticles to reduce LNP‐induced inflammation while retaining mRNA delivery. Results are validated in vitro and in three animal models of inflammation and autoimmunity in vivo.
Ajay S. Thatte, Benjamin E. Nachod, Julia Baena, Jenna Muscat‐Rivera, Lesley Chaboub, Hannah C. Safford, Hannah C. Geisler, Hannah M. Yamagata, Melgious J. Y. Ang, Michael Kegel, Alexandre Poirier, Elaine R. Tong, Zhe Zhong, Qiangqiang Shi, Jinjin Wang, Elisa Battistini, Ye Zeng, Alex G. Hamilton, Kelsey L. Swingle, Drew Weissman, Jilian R. Melamed, Michael J. Mitchell   +21 more
wiley   +1 more source

Chloride Ions: Essential Agents for Achieving Spontaneous Delamination of MXene

Advanced Materials, EarlyView.
This work first identifies chloride ions as essential agents for spontaneous MXene delamination. Without Cl−, etched Ti3C2Tx remains multilayered; with Cl−, interlayer modification enables Li+ intercalation and osmotic swelling. The SPEED process couples HF‐assisted Al extraction, Cl−‐mediated interlayer expansion, and Li+‐driven swelling to produce ...
Sukhyeun Jang, Yong‐Jae Kim, Incheol Jeong, Minju Kim, Jaewoong Lee, Jihan Kim, Ki‐Min Roh, Kang Taek Lee, Seon Joon Kim, Yonghee Lee, Chi Won Ahn, Hee‐Tae Jung   +11 more
wiley   +1 more source

Polymeric Sorbents as Energy‐Efficient Alternative to Cryogenic Distillation for Light Hydrocarbon Purification

Advanced Materials, EarlyView.
The transition from cryogenic distillation to polymeric sorbents for light hydrocarbon purification is crucial for energy and environmental sustainability. The polymeric sorbents are engineered to separate gas mixtures based on their specific properties.
Kelechi Festus, Ankit Mondal, Suman Mandal, Jazmine Aiya D. Marquez, Arnab Ghosh, Aishi Sikdar, Urme Podder, Ahana Sarkar, Qingsheng Wang, Hong‐Cai Zhou   +9 more
wiley   +1 more source

Engineering the Assembly Freedom of Donor–Acceptor Type Self‐Assembled Monolayers Toward Efficient and Stable Flexible Perovskite Photovoltaics

Advanced Materials, EarlyView.
Assembly freedom engineering breaks the vertical alignment constraint of donor–acceptor self‐assembled monolayers, tuning their assembly freedom to achieve quasi‐random molecular orientation. This strategy simultaneously boosts interfacial charge transport and mechanical robustness, enabling high‐efficiency and mechanically stable flexible perovskite ...
Biao Zhou, Guosen Zhang, Hao Wang, Juntao Zhao, Ruijia Zhang, Hong Zhang, Mingwei An, Yue Wang, Yang Wang, Wallace C. H. Choy   +9 more
wiley   +1 more source

Specific Position of Halogen in Crystalline TADF Scintillators Enables Efficient Triplet Harvesting Through Vibrational Modulation of Spin–Orbit Coupling

Advanced Materials, EarlyView.
Specific ortho‐halogenation transforms crystalline TADF emitters into efficient organic scintillators. Fluorine reduces the effective singlet–triplet separation, while chlorine combines near‐degenerate excited states with vibrational modulation of spin–orbit coupling.
Illia E. Serdiuk, Michał Mońka, Artur Sikorski, Konrad J. Drozdowski, Mohanad S. Eid, Krzysztof Wisniewski, Damian Trzybiński, Marcin E. Witkowski, Winicjusz Drozdowski   +8 more
wiley   +1 more source

Tuning Hydrophilic–Hydrophobic Properties of PLA Films Through Surface Fluorination and Drying

Physchem
Polylactic acid (PLA) films were directly fluorinated using fluorine gas at room temperature under varying conditions: fluorine concentrations of 190–760 Torr and reaction times of 10–60 min. Some of the fluorinated samples were subsequently dried at 70 °
Zhipeng He, Jae-Ho Kim, Susumu Yonezawa
doaj   +1 more source

Electrolyte Design for Fast‐Charging Lithium‐Based Batteries

Advanced Materials, EarlyView.
A decade of progress in fast‐charging electrolytes for lithium batteries is reviewed. Electrolyte design strategies spanning solvents, salts, additives, and advanced systems, such as localized high‐concentration electrolytes (LHCEs), are summarized. Advanced diagnostic tools for lithium plating and interphase chemistry are discussed, with perspectives ...
Chen Liu, Zehao Cui, Arumugam Manthiram
wiley   +1 more source

Biocatalytic enantioselective C(sp3)–H fluorination enabled by directed evolution of nonheme Fe enzymes [PDF]

Due to the scarcity of C–F bond forming enzymatic activities in nature and the contrasting ubiquity of organofluorine moieties in bioactive compounds, developing new biocatalytic fluorination reactions represents a preeminent challenge in enzymology ...
Fangqiu, Gao, Liu-Peng, Zhao, Peng, Liu, Rui, Guo, Yongda, Zhang, Binh Khanh, Mai, Lida, Cheng, Yang, Yang, Yunlong, Zhao, Hao, Wu   +9 more
core   +2 more sources