Results 61 to 70 of about 8,763 (265)
F1000Research, 2014 Fluorination has been widely used in chemical synthesis, but is rare in nature. The only known biological fluorination scope is represented by the fl pathway from Streptomyces cattleya that produces fluoroacetate (FAc) and 4-fluorothreonine (4-FT).
Yaya Wang, Zixin Deng, Xudong Qu
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Advanced Materials, EarlyView.The field of polymer thermoelectrics is entering a new era, featuring breakthroughs in addressing the conventional performance disparity between p‐type and n‐type polymers, pioneering doping frontiers, and sophisticated decoupling strategies. This review explores innovations in molecular design and superior stabilities, bridging the gap from ...
Suhao Wang
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Synthesis of thorium tetrafluoride (ThF4) by ammonium hydrogen difluoride (NH4HF2)
Nuclear Engineering and Technology, 2019 The present study aims to investigate the fluorination of thorium oxide (ThO2) by ammonium hydrogen difluoride (NH4HF2). Fluorination was performed at room temperature by mixing ThO2 and NH4HF2 at different molar ratios, which was then left to react for ...
Che Nor Aniza Che Zainul Bahri +2 more
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Advanced Materials, EarlyView.The energetic offset between the donor and the acceptor components in organic photoactive layers is central to the tradeoff between photovoltage and photocurrent losses. This Perspective covers the most important issues surrounding this topic in non‐fullerene acceptor blends, from the difficulty of accurately determining state energies and driving ...
Dieter Neher, Manasi Pranav
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Design and Experimental Investigation of Fluoride Volatility Fluidized Bed Reactor
Yuanzineng kexue jishuChina’s nuclear energy development is implemented through a three-step strategy of pressurized water reactor-fast reactor-fusion reactor, accompanied by closed nuclear fuel cycle technology.
ZHANG Lixin, ZHU Yingxi, YUAN Zhiliang, WU Yingjie, ZHANG Shengwei, WANG Wenhui, YANG Tinggui
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Fluorination with Complex Fluorine Compounds
The Journal of the Society of Chemical Industry, Japan, 1969 鉄,アルミニウム,アンチモン,ケイ素,チタンなどの6配位錯フッ化物によるハロゲン交換フッ素化反応について研究した。フッ素化の対象としては,四塩化炭素,クロロホルム,ヘキサクロルエタンなどの有機塩素化合物をえらび,オートクレープ中で250ないし350℃で2時間ないし4時間反応させた。この結果,鉄,アンチモン,アルミニウムなどの錯フッ化勃の活性が大きく,ケイ素の錯フッ化物の活性はこれらについだ。これに対し,チタソの錯フッ化物は不活性であることがわかった。鉄,アンチモン,アルミニウムの錯フッ化物の活性が大きいことは,これら錯フッ化物がリガンド交換活性な外軌道または高スピン錯塩であることによるものと考えられる。実際に,反応後の固体をX線回折分析により調べたところ,低配位錯塩NaAIF4 ...
Susumu OKAZAKI, Tadayoshi WATANABE
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Advanced Materials, EarlyView.Ultrathin lithium metal anodes (≤15 µm) offer a promising route to high‐energy‐density batteries due to their high capacity and low potential. This review presents design principles for ultrathin Li, evaluates fabrication strategies, and discusses challenges in liquid and solid‐state cells.
Cheng Wang +9 more
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Controlled Hydrophilic–Hydrophobic Transition of PET Films via Fluorination and Drying
PhyschemPolyethylene terephthalate (PET) films were modified by direct fluorination using fluorine gas at room temperature and 660 torr for reaction times ranging from 10 min to 5 h. Some of the fluorinated samples were dried at 70 °C for 7 days.
Zhipeng He, Jae-Ho Kim, Susumu Yonezawa
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Advanced Materials, EarlyView.Molecularly engineered self‐assembled monolayers (SAMs) featuring extended conjugated terminals facilitate superior interfacial coupling with the organic solar cell active layer. By physically anchoring the local morphology, this design suppresses thermal degradation, allowing devices to operate at 85°C for 150 h before degrading to 90% of their ...
Gengxin Du +17 more
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Advanced Materials Interfaces, EarlyView.Interfacial charge transfer and low‐resistance interphase formation between PEO‐based polymer and Li10GeP2S12 solid electrolytes are investigated using multi‐electrode impedance spectroscopy and advanced analytical techniques such as XPS and ToF‐SIMS.
Ujjawal Sigar +6 more
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